High-precision analysis of calcium isotopes using a Nu Sapphire collision cell (CC)-MC-ICP-MS
文献类型：期刊论文
| 作者 | Gao, Bing-Yu2; Su, Ben-Xun1,2; Li, Wen-Jun2; Yuan, Meng1,2; Sun, Jian3; Zhao, Ye4; Liu, Xia1,2 |
| 刊名 | JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
 |
| 出版日期 | 2022-10-07 |
| 卷号 | 37期号:10页码:2111-2121 |
| ISSN号 | 0267-9477 |
| DOI | 10.1039/d2ja00150k |
| 英文摘要 | This study presents high-precision analyses of calcium (Ca) isotope ratios using a collision-cell multi-collector inductively coupled plasma mass spectrometer (CC-MC-ICP-MS, Nu Sapphire). This instrument allows Ca isotope measurement in the low resolution mode, requiring much less sample compared with TIMS and conventional MC-ICP-MS, and has additional measurement capability of both radiogenic (epsilon Ca-40) and stable isotope ratios (delta Ca-44/40 and delta Ca-44/42). The effects of several factors on the precision and accuracy of Ca isotopic data were evaluated, including the total Ca concentration, Ca intensity mismatch between the sample and standard, HNO3 molarity mismatch between the sample and standard, and the presence of matrix elements. High precision was obtained on 100 ng g(-1) Ca samples (i.e., for 6 replicates similar to 600 ng of Ca). Accurate measurements require the following conditions: (1) Ca intensities matched within 3% between the sample and standard, (2) low contents of Sr, Mg and Cr (Sr/Ca, Mg/Ca and Cr/Ca ratios need to be lower than 0.01%, and K/Ca, Al/Ca, Ti/Ca and Cr/Ca ratios <1%). Eleven standard reference materials analyzed using the established method yield highly consistent Ca isotope results with literature values. The long-term external precisions are higher than 0.07 parts per thousand (2 SD) for delta Ca-44/40 and higher than 0.05 parts per thousand (2 SD) for delta Ca-44/42. The slope of the fractionation line between delta Ca-44/40 and delta Ca-44/42 is 1.9616 +/- 0.0794, within the error of the slope value from the exponential law. |
| WOS关键词 | MC-ICP-MS ; CA ISOTOPES ; IGNEOUS ROCKS ; FRACTIONATION ; MANTLE ; DELTA-CA-44/40 ; CONSTRAINTS ; SYSTEMATICS ; CARBONATES ; INSIGHTS |
| 资助项目 | Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences[TEC 202103] ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; State Key Laboratory of Lithospheric Evolution[SKL-K202202] |
| WOS研究方向 | Chemistry ; Spectroscopy |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000857539300001 |
| 资助机构 | Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; State Key Laboratory of Lithospheric Evolution ; State Key Laboratory of Lithospheric Evolution ; State Key Laboratory of Lithospheric Evolution ; State Key Laboratory of Lithospheric Evolution ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; State Key Laboratory of Lithospheric Evolution ; State Key Laboratory of Lithospheric Evolution ; State Key Laboratory of Lithospheric Evolution ; State Key Laboratory of Lithospheric Evolution ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; State Key Laboratory of Lithospheric Evolution ; State Key Laboratory of Lithospheric Evolution ; State Key Laboratory of Lithospheric Evolution ; State Key Laboratory of Lithospheric Evolution ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; Youth Innovation Promotion Association, Chinese Academy of Sciences ; State Key Laboratory of Lithospheric Evolution ; State Key Laboratory of Lithospheric Evolution ; State Key Laboratory of Lithospheric Evolution ; State Key Laboratory of Lithospheric Evolution |
| 源URL | [http://ir.iggcas.ac.cn/handle/132A11/108365]  |
| 专题 | 地质与地球物理研究所_中国科学院矿产资源研究重点实验室 |
| 通讯作者 | Gao, Bing-Yu |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Geol & Geophys, Key Lab Mineral Resources, Beijing 100029, Peoples R China 3.Chinese Acad Geol Sci, Inst Geol, MNR Key Lab Isotope Geol, Key Lab Deep Earth Dynam,Minist Nat Resources, Beijing 100037, Peoples R China 4.Nu Instruments, Unit 74 Clywedog Rd South,Wrexham Ind Estate, Wrexham LL13 9XS, Wales |
| 推荐引用方式 GB/T 7714 | Gao, Bing-Yu,Su, Ben-Xun,Li, Wen-Jun,et al. High-precision analysis of calcium isotopes using a Nu Sapphire collision cell (CC)-MC-ICP-MS[J]. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY,2022,37(10):2111-2121. |
| APA | Gao, Bing-Yu.,Su, Ben-Xun.,Li, Wen-Jun.,Yuan, Meng.,Sun, Jian.,...&Liu, Xia.(2022).High-precision analysis of calcium isotopes using a Nu Sapphire collision cell (CC)-MC-ICP-MS.JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY,37(10),2111-2121. |
| MLA | Gao, Bing-Yu,et al."High-precision analysis of calcium isotopes using a Nu Sapphire collision cell (CC)-MC-ICP-MS".JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY 37.10(2022):2111-2121. |
入库方式： OAI收割
来源：地质与地球物理研究所
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