中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Sources of rare earth elements and yttrium in the early Cambrian phosphorites in Zhijin, southwest China

文献类型:期刊论文

作者Shengwei Wu; Haifeng Fan; Yong Xia; Qingtian Meng; Xingxiang Gong; Shan He; Xiqiang Liu; Haiying Yang; Hanjie Wen
刊名Ore Geology Reviews
出版日期2022
卷号150页码:105146
关键词Rey Sources Early Cambrian Phosphorites Granite Weathering
DOI10.1016/j.oregeorev.2022.105146
英文摘要

The early Cambrian Zhijin phosphorite in Guizhou province, China, has high rare earth elements and yttrium (REY) contents of up to 2500 ppm, with heavy REY (HREY) accounting for ∼30 % of the total REY. However, their REY sources are not well-determined. Herein, elemental geochemistry and Sr–Nd isotopes of phosphorites in four sections from the Zhijin phosphorite ore area were investigated, primarily to constrain the contributions of seawater and terrestrial REY sources to the REY enrichment in these phosphorites. Zhijin phosphorites have high Y/Ho (45–63) and seawater signature’s 87Sr/86Sr(i) ratios (0.7085–0.7092), suggesting a partial contribution from seawater-sourced REY. On the other hand, Zhijin phosphorites have εNd(t) values of −8.6 – −6.8, indicative of the great influence from continental weathering. The Y/Ho ratios exhibit negative correlations with their Zr contents and SmN/YbN ratios; meanwhile the 87Sr/86Sr(i) ratios exhibit positive correlations with their Sr contents and REY contents, indicating that terrestrial source contributions played an important role in REY enrichment in Zhijin phosphorites. Furthermore, the provenance of Zhijin shales indicates the terrigenous granite weathering, during which the regolith-hosted REY could be transported to Zhijin shallow seawater, providing abundant REY to Zhijin phosphorites. We proposed that the REY enrichment in Zhijin phosphorites could be associated with high REY seawater induced by granite weathering. This study provides a new perspective on the relationship between granite weathering and marine REY deposition, which may be a common phenomenon in geological history but remains to be fully investigated in future.

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语种英语
源URL[http://ir.gyig.ac.cn/handle/42920512-1/13528]  
专题地球化学研究所_矿床地球化学国家重点实验室
作者单位1.State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
2.University of Chinese Academy of Sciences, Beijing 100049, China
3.No. 104 Geological Team, Guizhou Bureau of Geology and Mineral Exploration & Development, Guiyang 550081, China
4.Reserve Bureau of Land and Mineral Resources of Guizhou Province, Guiyang 550081, China
5.School of Earth Sciences, Yunnan University, Kunming 650500, China
6.School of Earth Sciences and Resources, Chang’an University, Xi’an 710054, China
推荐引用方式
GB/T 7714
Shengwei Wu,Haifeng Fan,Yong Xia,et al. Sources of rare earth elements and yttrium in the early Cambrian phosphorites in Zhijin, southwest China[J]. Ore Geology Reviews,2022,150:105146.
APA Shengwei Wu.,Haifeng Fan.,Yong Xia.,Qingtian Meng.,Xingxiang Gong.,...&Hanjie Wen.(2022).Sources of rare earth elements and yttrium in the early Cambrian phosphorites in Zhijin, southwest China.Ore Geology Reviews,150,105146.
MLA Shengwei Wu,et al."Sources of rare earth elements and yttrium in the early Cambrian phosphorites in Zhijin, southwest China".Ore Geology Reviews 150(2022):105146.

入库方式: OAI收割

来源:地球化学研究所

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