Transition-metal-free electrochemical-induced active C(sp(3))-H functionalization
文献类型：期刊论文
| 作者 | Ma, Xiaolong2,3,4; Wei, Jinfeng2; Yang, Xu2; Xu, Huajin1,2; Hu, Yi1,2 |
| 刊名 | GREEN CHEMISTRY LETTERS AND REVIEWS
 |
| 出版日期 | 2023-01-02 |
| 卷号 | 16期号:1页码:33 |
| ISSN号 | 1751-8253 |
| 关键词 | C(sp3)-H functionalization electrochemistry transition-metal-free |
| DOI | 10.1080/17518253.2022.2134740 |
| 通讯作者 | Xu, Huajin(201910006660@njtech.edu.cn) ; Hu, Yi(huyi@njtech.edu.cn) |
| 英文摘要 | Direct C-H bond functionalization is the most effective technique to construct C-X (X = C, N, O, S, etc.), which could simplify the conventional synthesis methods. Transition-metal-catalyzed C-H bond functionalization needs metal catalysts such as palladium, rhodium, iridium, cobalt, copper, etc., which is not conducive to its sustainable development. In recent years, C(sp(3))-H bond functionalization without transition metal catalyst has been studied increasingly. In the meantime, electrochemistry has become one of the most dynamic research fields in organic synthesis for the reason that it can substitute the traditional expensive and polluting metal salt oxidants (e.g. Cu2+, Ag+ salt) with current/electrons to act as a redox agent. So the applications of electrochemistry combined with transition-metal-free C(sp(3))-H bond functionalization to solve some long-standing challenges have gradually gotten more and more attention in recent years. In this review, the researches on transition-metal-free electrochemical-induced C(sp(3))-H bond functionalization from 2016 to now will be systematically presented and the future research hotspots and difficulties in this field will also be prospected. |
| WOS关键词 | C-H FUNCTIONALIZATION ; N-MANNICH BASES ; ELECTROORGANIC CHEMISTRY ; BENZYLIC C(SP(3))-H ; OXIDATION ; AMINATION ; ACETOXYLATION ; AMINES ; ACIDS ; LACTONIZATION |
| 资助项目 | National Natural Science Foundation of China ; [22001123] ; [22178174] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| 出版者 | TAYLOR & FRANCIS LTD |
| WOS记录号 | WOS:000905679800001 |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/304022]  |
| 专题 | 中国科学院上海药物研究所 |
| 通讯作者 | Xu, Huajin; Hu, Yi |
| 作者单位 | 1.Nanjing Tech Univ, Sch Pharmaceut Sci, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China 2.Nanjing Tech Univ, Sch Pharmaceut Sci, State Key Lab Mat Oriented Chem Engn, Nanjing, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Mat Med SIMM, Key Lab Receptor Res, Shanghai, Peoples R China 4.Univ Chinese Acad Sci, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Xiaolong,Wei, Jinfeng,Yang, Xu,et al. Transition-metal-free electrochemical-induced active C(sp(3))-H functionalization[J]. GREEN CHEMISTRY LETTERS AND REVIEWS,2023,16(1):33. |
| APA | Ma, Xiaolong,Wei, Jinfeng,Yang, Xu,Xu, Huajin,&Hu, Yi.(2023).Transition-metal-free electrochemical-induced active C(sp(3))-H functionalization.GREEN CHEMISTRY LETTERS AND REVIEWS,16(1),33. |
| MLA | Ma, Xiaolong,et al."Transition-metal-free electrochemical-induced active C(sp(3))-H functionalization".GREEN CHEMISTRY LETTERS AND REVIEWS 16.1(2023):33. |
入库方式： OAI收割
来源：上海药物研究所
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