Insights into the reaction mechanism of toluene oxidation by isotope dynamic experiment and the kinetics over MCeZr/TiO2 (M = Cu, Mn, Ni, Co and Fe) catalysts
文献类型：期刊论文
| 作者 | Zhang, Zirui1; Hu, Guangtao; Zhao, Chenchen4; Wei XL(魏小林) ; Dou, Baojuan4; Liang, Wenjun2; Bin F(宾峰)
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| 刊名 | FUEL
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| 出版日期 | 2023-06-01 |
| 卷号 | 341页码:127760 |
| 关键词 | Toluene removal Kinetics Freeman Carroll Infrared spectrum Isotopically labeled oxygen |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2023.127760 |
| 英文摘要 | Catalytic properties of multiple metals deposited on TiO2 nanoparticles were investigated in the oxidation of toluene. Isovolume impregnation method prepared the catalysts containing Cu, Mn, Ni, Co, and Fe deposited on TiO2, including CeO2 and ZrO2. The effects of loaded metal oxides on the structure and activity of initial catalysts were investigated using various characterization techniques. Toluene's removal efficiency and CO2 selectivity in the catalyst system were classified as follows: CuCeZr/T > MnCeZr/T > NiCeZr/T > CoCeZr/T > FeCeZr/T. Presence of water vapor exhibits an inhibitory effect on the conversion of toluene, which diminishes at higher temperatures. One contribution of this paper is to obtain the oxidation pathway of toluene and the relationship between the activation energy of all inclusive and elementary reactions based on the variation of infrared spectrum using Freeman Carroll method. Another contribution is to clarify the share of Langmuir Hinshelwood and Mars van Krevelen mechanisms during the oxidation of toluene over CuCeZr/T catalyst by transient response experiments of isotopically labeled oxygen. These findings provide a feasible method for the design and synthesis of transition metal oxide catalysts for industrial applications. |
| 分类号 | 一类 |
| WOS研究方向 | Energy & Fuels ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000950542600001 |
| 资助机构 | Guangxi Key Research and Development Program [2021AB25028, 2021004] ; Key R & D Program of ShaanXi Province [2023 YBSF 442] |
| 其他责任者 | Hu, GT (corresponding author), Yulin Univ, Sch Energy Engn, Yulin 719000, Peoples R China. ; Bin, F (corresponding author), Chinese Acad Sci, Inst Mech, State Key Lab High Temp Gas Dynam, Beijing 100190, Peoples R China. |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/91802]  |
| 专题 | 力学研究所_高温气体动力学国家重点实验室 |
| 作者单位 | 1.Yulin Univ, Sch Energy Engn, Yulin 719000, Peoples R China 2.Tianjin Univ Sci & Technol, Tianjin 300457, Peoples R China 3.Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China 4.Chinese Acad Sci, Inst Mech, State Key Lab High Temp Gas Dynam, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zirui,Hu, Guangtao,Zhao, Chenchen,et al. Insights into the reaction mechanism of toluene oxidation by isotope dynamic experiment and the kinetics over MCeZr/TiO2 (M = Cu, Mn, Ni, Co and Fe) catalysts[J]. FUEL,2023,341:127760. |
| APA | Zhang, Zirui.,Hu, Guangtao.,Zhao, Chenchen.,魏小林.,Dou, Baojuan.,...&宾峰.(2023).Insights into the reaction mechanism of toluene oxidation by isotope dynamic experiment and the kinetics over MCeZr/TiO2 (M = Cu, Mn, Ni, Co and Fe) catalysts.FUEL,341,127760. |
| MLA | Zhang, Zirui,et al."Insights into the reaction mechanism of toluene oxidation by isotope dynamic experiment and the kinetics over MCeZr/TiO2 (M = Cu, Mn, Ni, Co and Fe) catalysts".FUEL 341(2023):127760. |
入库方式： OAI收割
来源：力学研究所
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