The performance of an all fibered near-infrared (NIR) single-channel frequency-division multiplexing wavelength-modulated laser heterodyne radiometer (FDM WM-LHR) is demonstrated in ground-based solar occultation mode. The system modulates the laser through the high-frequency signal output by the lock-in amplifier to replace the traditional chopper modulation, making it more stable and compact. Moreover, per-sonal computers are used to simultaneously control the operating current of two distributed feedback (DFB) lasers through a general purpose interface bus-universal serial bus (GPIB-USB), thereby controlling the central wavelength of the laser at 1602.88 and 1653.727 nm, which serve as the absorption lines for the local oscillator detection of the two main greenhouse gases: CO2 and CH4. Firstly, the performance of traditional laser hetero-dyne radiometer (LHR) and the wavelength-modulated laser heterodyne radiometer (WM-LHR) are compared.The results reveal that both the radiometers have an optimized 2f signal when the modulation amplitude m = 2.2. In the actual measurement, 0.25 V and 0.21 V are selected as the modulation amplitude of the laser for the detection of CH4 and CO2. Under the same experimental parameters, at 1602.88 nm, the signal-to-noise ratio (SNR) for the 2f signal of CO2 in the WM-LHR system is 500.24, while that for the direct absorption signal (DAS) of CO2 in the traditional LHR system is 337.94. At 1653.727 nm, the SNR for the 2f signal in the WM-LHR system and the DAS of CH4 in the traditional LHR system are 512.04 and 389.58, respectively. Obviously, the SNR for the WM-LHR system is greatly improved. Finally, the application of frequency-division multiplexing (FDM) technology in the WM-LHR system is discussed. The modulation frequency of the two lasers should be appro-priately selected to avoid interference between the signals. Overall, the results show that the FDM WM-LHR system can not only detect multiple gases simultaneously but also reduce the implementation cost of the ground-based radiometer. In addition, this study provides useful insights on planetary atmosphere exploration.