Atmospheric effects including absorption and scattering, and turbulence could introduce signal power loss and severe mode crosstalk for the orbital angular momentum (OAM)-based free-space optical communication (FSOC). Therefore, it is of great significance to simultaneously increase signal power and mitigate mode crosstalk. In this paper, for the OAM beam from a coherent laser array with a discrete vortex (CLA-DV) based on coherent beam combining, we investigate its propagation characteristics by employing theoretical derivation and the random phase screens simulation in atmospheric propagation, respectively. The probability density and OAM spectrum are given and compared for CLA-DV and Gaussian vortex beam. The results demonstrate that the Gaussian vortex beam exhibits smaller mode crosstalk under weak atmospheric turbulence conditions, while CLA-DV shows a good performance on crosstalk mitigation for strong atmospheric turbulence conditions in long-distance links. Furthermore, with a specially designed radial phase-locked Gaussian laser array composed of two orthogonal polarized coherent laser arrays carrying different OAM states, a scheme of optical communication system possessing simultaneously polarization-division multiplexing and OAM multiplexing is proposed. The normalized energy weight matrices of all 16 non-zeroth-order OAM modes are numerically calculated. To verify the feasibility of the proposed scheme, the performance of an eight-bit grayscale Lena image facing various atmosphere turbulences is evaluated. The quality of transmitted images becomes worse with the turbulence strength and transmission distance increase, which is confirmed by the trend of average optical signal error rates. This work will provide theoretical insight for improving the performance of OAM-based FSOC under scattering conditions.