Anion-Dependent Formation of Helicates versus Mesocates of Triple-Stranded M2L3 (M = Fe2+, Cu2+) Complexes
文献类型：期刊论文
| 作者 | Cui FJ(崔凤娟)1,2; Li SG(李少光)1,2; Jia CD(贾传东)1,2; Mathieson, Jennifer S.3; Cronin, Leroy3; Yang XJ(杨晓娟)1 ; Wu B(吴彪)1
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| 刊名 | Inorganic Chemistry
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| 出版日期 | 2012 |
| 卷号 | 51期号:1页码:179-187 |
| ISSN号 | 0020-1669 |
| 通讯作者 | 吴彪 |
| 英文摘要 | A series of dinuclear triple-stranded complexes, [Fe2L3⊃X]X6 [X = BF4– (1), ClO4– (2)], [Fe2L3⊃SO4]2(SO4)5 (3), [Fe2L3⊃Br](BPh4)6 (4), Fe2L3(NO3)Br6 (5), and [Cu2L3⊃NO3](NO3)6 (6), which incorporate a central cavity to encapsulate different anions, have been synthesized via the self-assembly of iron(II) or copper(II) salts with the N,N′-bis[5-(2,2′-bipyridyl)methyl]imidazolium bromide (LBr) ligand. X-ray crystallographic studies (for 1–4 and 6) and elemental analyses confirmed the cagelike triple-stranded structure. The anionic guest is bound in the cage and shows remarkable influence on the outcome of the self-assembly process with regard to the configuration at the metal centers. The mesocates (with different configurations at the two metal centers) have formed in the presence of large tetrahedral anions, while helicates (with the same configuration at both metal centers) were obtained when using the relatively smaller spherical or trigonal-planar anions Br– or NO3–. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Grant 20872149);WestCHEM and the EPSRC for funding |
| 语种 | 英语 |
| WOS记录号 | WOS:000298712000027 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://210.77.64.217/handle/362003/3830]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Univ Glasgow, Sch Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland |
| 推荐引用方式 GB/T 7714 | Cui FJ,Li SG,Jia CD,et al. Anion-Dependent Formation of Helicates versus Mesocates of Triple-Stranded M2L3 (M = Fe2+, Cu2+) Complexes[J]. Inorganic Chemistry,2012,51(1):179-187. |
| APA | Cui FJ.,Li SG.,Jia CD.,Mathieson, Jennifer S..,Cronin, Leroy.,...&Wu B.(2012).Anion-Dependent Formation of Helicates versus Mesocates of Triple-Stranded M2L3 (M = Fe2+, Cu2+) Complexes.Inorganic Chemistry,51(1),179-187. |
| MLA | Cui FJ,et al."Anion-Dependent Formation of Helicates versus Mesocates of Triple-Stranded M2L3 (M = Fe2+, Cu2+) Complexes".Inorganic Chemistry 51.1(2012):179-187. |
入库方式： OAI收割
来源：兰州化学物理研究所
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