Photocatalytic hydrogen evolution under visible light irradiation by the polyoxometalate alpha-[AlSiW11(H2O)O-39](5-) -Eosin Y system
文献类型：期刊论文
| 作者 | Liu X(刘兴)1; Li YX(李越湘)1; Peng SQ(彭绍琴)1; Lu GX(吕功煊)2 ; Li SB(李树本)2
|
| 刊名 | International Journal of Hydrogen Energy
 |
| 出版日期 | 2012 |
| 卷号 | 37期号:17页码:12150-12157 |
| 关键词 | Dye Polyoxometalate Sensitization Chemical linking Hydrogen evolution |
| ISSN号 | 0360-3199 |
| 通讯作者 | 李越湘 |
| 英文摘要 | It is important to construct a stable and efficient dye sensitization system for visible-light photocatalytic hydrogen evolution. Eosin Y (EY)-sensitized α-[AlSiW11(H2O)O39]5− (AlSiW11) (an Al3+ substituted Keggin polyoxometalate (POM)) for the hydrogen evolution under visible light irradiation (λ > 420 nm) has been carried out in the presence of triethanolamine as electron donor and Pt as co-catalyst. EY can coordinate with AlSiW11. The coordination association between AlSiW11 and EY is beneficial to the charge transfer from EY to AlSiW11 and to stability of EY. The system displays efficient and stable photocatalytic hydrogen evolution. The average apparent quantum efficiency and turnover number of EY during 20 h irradiation (λ > 420 nm) are 10.3% and 473, respectively. The highest quantum efficiency amounts to 28.0% under 520 nm monochromatic light irradiation. The present study highlights linking between dye and POM molecule as a way to develop new visible-light stable photocatalyst or system. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Nature Science Foundation of China (21163012);the National Basic Research Program of China (2009CB220003);the Research Fund of Education Ministry of Jiangxi, China (GJJ09041) |
| 语种 | 英语 |
| WOS记录号 | WOS:000309024700014 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://210.77.64.217/handle/362003/3841]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
| 作者单位 | 1.Nanchang Univ, Dept Chem, Nanchang 330031, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu X,Li YX,Peng SQ,et al. Photocatalytic hydrogen evolution under visible light irradiation by the polyoxometalate alpha-[AlSiW11(H2O)O-39](5-) -Eosin Y system[J]. International Journal of Hydrogen Energy,2012,37(17):12150-12157. |
| APA | Liu X,Li YX,Peng SQ,Lu GX,&Li SB.(2012).Photocatalytic hydrogen evolution under visible light irradiation by the polyoxometalate alpha-[AlSiW11(H2O)O-39](5-) -Eosin Y system.International Journal of Hydrogen Energy,37(17),12150-12157. |
| MLA | Liu X,et al."Photocatalytic hydrogen evolution under visible light irradiation by the polyoxometalate alpha-[AlSiW11(H2O)O-39](5-) -Eosin Y system".International Journal of Hydrogen Energy 37.17(2012):12150-12157. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。