Bronsted Acidic Ionic Liquids as Efficient and Recyclable Catalysts for the Carbonylation of Formaldehyde
文献类型：期刊论文
| 作者 | Song HY(宋河远) ; Li Z(李臻); Chen J(陈静); Xia CG(夏春谷); Li Z(李臻); Chen J(陈静)
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| 刊名 | Catalysis Letters
 |
| 出版日期 | 2012 |
| 卷号 | 142期号:1页码:81-86 |
| 关键词 | Formaldehyde Carbonylation Methyl glycolate Ethylene glycol Ionic liquids |
| ISSN号 | 1011-372X |
| 通讯作者 | 李臻 ; 陈静 |
| 英文摘要 | Methyl glycolate (MG), as a precursor to ethylene glycol (EG), was synthesized by an efficient and eco-friendly procedure of one-pot, two-step, sequential reaction, including carbonylation and esterification from HCHO with Brönsted acidic ionic liquids (BAILs) as catalysts. MG was obtained in high yield under mild conditions. In addition, the catalyst could be recycled eight times after separating the unreacted materials and products from the reaction system by distillation under vacuum and no significant decrease in catalytic activity was observed. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | National Basic Research Program of China (973 Program) 2011CB201404;the Key Project of the National Twelfth-Five Year Research Program of China 2011BAE17B00 |
| 语种 | 英语 |
| WOS记录号 | WOS:000299919700010 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://210.77.64.217/handle/362003/3890]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Li Z(李臻); Chen J(陈静) |
| 作者单位 | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song HY,Li Z,Chen J,et al. Bronsted Acidic Ionic Liquids as Efficient and Recyclable Catalysts for the Carbonylation of Formaldehyde[J]. Catalysis Letters,2012,142(1):81-86. |
| APA | Song HY,Li Z,Chen J,Xia CG,李臻,&陈静.(2012).Bronsted Acidic Ionic Liquids as Efficient and Recyclable Catalysts for the Carbonylation of Formaldehyde.Catalysis Letters,142(1),81-86. |
| MLA | Song HY,et al."Bronsted Acidic Ionic Liquids as Efficient and Recyclable Catalysts for the Carbonylation of Formaldehyde".Catalysis Letters 142.1(2012):81-86. |
入库方式： OAI收割
来源：兰州化学物理研究所
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