Platinum-catalyzed michael addition and cyclization of tertiary amines with nitroolefins by dehydrogenation of r,β-sp3 C-H bonds
文献类型：期刊论文
| 作者 | Xia XF(夏晓峰) ; Shu XZ(舒兴中) ; Ji KG(纪克攻) ; Yang YF(杨艳芳) ; Ali Shaukat ; Liu XY(刘雪原) ; Liang YM(梁永民) |
| 刊名 | Journal of Organic Chemistry
 |
| 出版日期 | 2010 |
| 卷号 | 75页码:2893-2902 |
| ISSN号 | 0022-3263 |
| 通讯作者 | 梁永民 |
| 中文摘要 | A mild platinum-catalyzed oxidative dehydrogenation of R,β-C(sp3)-H bonds of tertiary amines in thepresence of ambient oxygen is revealed, and the in situ formed enamines subsequently reacting withvarious nitroolefins resulted in the development of two one-pot synthetic protocols involving Michaeladdition-elimination and Michael addition-cyclization. By using different functionalized nitroolefinscompatible with the current oxidative conditions, two types of structurally divergent products,trisubstituted enamines and chromano[2,3-b]piperidines, could be expediently accessed, respectively. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the National Science Foundation (NSF-20732002, NSF-20090443, NSF-20872052) |
| 语种 | 英语 |
| 公开日期 | 2013-10-15 |
| 源URL | [http://210.77.64.217/handle/362003/3950]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Xia XF,Shu XZ,Ji KG,et al. Platinum-catalyzed michael addition and cyclization of tertiary amines with nitroolefins by dehydrogenation of r,β-sp3 C-H bonds[J]. Journal of Organic Chemistry,2010,75:2893-2902. |
| APA | 夏晓峰.,舒兴中.,纪克攻.,杨艳芳.,Ali Shaukat.,...&梁永民.(2010).Platinum-catalyzed michael addition and cyclization of tertiary amines with nitroolefins by dehydrogenation of r,β-sp3 C-H bonds.Journal of Organic Chemistry,75,2893-2902. |
| MLA | 夏晓峰,et al."Platinum-catalyzed michael addition and cyclization of tertiary amines with nitroolefins by dehydrogenation of r,β-sp3 C-H bonds".Journal of Organic Chemistry 75(2010):2893-2902. |
入库方式： OAI收割
来源：兰州化学物理研究所
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