Synthesis of five- and six-membered dihalogenated heterocyclic compounds by electrophile-triggered cyclization
文献类型：期刊论文
| 作者 | Ji KG(纪克攻) ; Zhu HT(祝海涛) ; Yang F(杨芳) ; Ali Shaukat ; Xia XF(夏晓峰) ; Yang YF(杨艳芳) ; Liu XY(刘雪原) ; Liang YM(梁永民) |
| 刊名 | Journal of Organic Chemistry
 |
| 出版日期 | 2010 |
| 卷号 | 75页码:5670-5678 |
| ISSN号 | 0022-3263 |
| 通讯作者 | 梁永民 |
| 中文摘要 | Highly substituted dihalogenated dihydrofurans, dihydropyrroles, and dihydro-2H-pyrans bearingalkyl, vinyl, aryl, and heteroaryl moieties can be prepared in good to excellent yields (up to 99%) byallowing 1,4-butyne-diol, 4-aminobut-2-yn-1-ol, and pent-2-yne-1,5-diol derivatives to react withdifferent electrophiles (I2, IBr, and ICl) at room temperature. Both halogen atoms generated fromelectrophiles were used effectively. The resulting halides can be further exploited by using palladium-catalyzed coupling reactions. The presence of trace amount of water is essential for this electrophilic cyclization. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the NSF (NSF-20732002, NSF-2087205, NSF-20090443);the Fundamental Research Funds for the Central Universities |
| 语种 | 英语 |
| WOS记录号 | WOS:000280798900025 |
| 公开日期 | 2013-10-15 |
| 源URL | [http://210.77.64.217/handle/362003/3951]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Ji KG,Zhu HT,Yang F,et al. Synthesis of five- and six-membered dihalogenated heterocyclic compounds by electrophile-triggered cyclization[J]. Journal of Organic Chemistry,2010,75:5670-5678. |
| APA | 纪克攻.,祝海涛.,杨芳.,Ali Shaukat.,夏晓峰.,...&梁永民.(2010).Synthesis of five- and six-membered dihalogenated heterocyclic compounds by electrophile-triggered cyclization.Journal of Organic Chemistry,75,5670-5678. |
| MLA | 纪克攻,et al."Synthesis of five- and six-membered dihalogenated heterocyclic compounds by electrophile-triggered cyclization".Journal of Organic Chemistry 75(2010):5670-5678. |
入库方式： OAI收割
来源：兰州化学物理研究所
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