Ionic Microporous Polymer Membranes for Advanced Gas Separations
文献类型：期刊论文
| 作者 | Han, Tianliang1,2; Cai, Zhili1; Wang, Can1; Zheng, Peijun1; Wu, Qi1; Liu, Lu1; Liu, Xinyu1,2; Weidman, Jennifer; Luo, Shuangjiang1,3 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2023-01-12 |
| 页码 | 12 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.2c04088 |
| 英文摘要 | Microporous polymers are uniquely attractive for membrane-mediated gas separations; however, conventional microporous polymers suffer a ubiquitous trade-off between gas permeability and selectivity, leading to bottlenecks in their practical applications. Functionalization of microporous polymers via molecule engineering is an effective way to enhance their gas separation performance and processability. This review outlines the research progress of ionization to improve the gas separation performance of typical microporous polymers (e.g., polymers of intrinsic microporosity (PIM), perfluorinated polymers, microporous polyimides, etc.) and summarizes the different ionization methods, including carboxylation, sulfonation, quaternization, and other ionization processes. Additionally, the review also explores the research progress of ionization to regulate the processability, microporosity, and gas separation properties of microporous polymers. Specifically, ionization can effectively tailor the microporosity, improve the solubility coefficients of gas molecules, especially CO2, and enhance gas selectivities. In addition, ionization can improve the processability of PIMs and enhance the membrane plasticization resistance. Ionic microporous polymers provide an essential platform for developing energy-efficient and high-performance gas separation membranes. |
| WOS关键词 | LINKED POLYIMIDE MEMBRANES ; HIGH-PERFORMANCE MEMBRANES ; CO2 SEPARATION ; TROGERS BASE ; INTRINSIC MICROPOROSITY ; 6FDA-DURENE POLYIMIDE ; TRADEOFF RELATIONS ; CROSS-LINKING ; UPPER-BOUNDS ; TEMPERATURE |
| 资助项目 | National Natural Science Foundation of China[22008243] ; National Natural Science Foundation of China[22090063] ; International Partner Program of CAS[122111KYSB20200035] ; Project of Stable Support for Youth Team in Basic Research Field of CAS[YSBR-017] ; Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering[2022SZ-TD014] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000920327400001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; International Partner Program of CAS ; Project of Stable Support for Youth Team in Basic Research Field of CAS ; Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/56712]  |
| 通讯作者 | Luo, Shuangjiang |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Beijing Key, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Shanxi Zheda Inst Adv Mat & Chem Engn, Taiyuan 030000, Shanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, Tianliang,Cai, Zhili,Wang, Can,et al. Ionic Microporous Polymer Membranes for Advanced Gas Separations[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2023:12. |
| APA | Han, Tianliang.,Cai, Zhili.,Wang, Can.,Zheng, Peijun.,Wu, Qi.,...&Luo, Shuangjiang.(2023).Ionic Microporous Polymer Membranes for Advanced Gas Separations.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,12. |
| MLA | Han, Tianliang,et al."Ionic Microporous Polymer Membranes for Advanced Gas Separations".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2023):12. |
入库方式： OAI收割
来源：过程工程研究所
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