CO2 Induces Symmetry Breaking in Layered Dipeptide Crystals
文献类型：期刊论文
| 作者 | Li, Xianbao1,2; Li, Qi1,3; Wu, Aoli1,2; Li, Junbai1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2022-12-01 |
| 页码 | 6 |
| 关键词 | Dipeptides Layer Stacking Piezoelectricity Supramolecular Assembly Symmetry Breaking |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.202214184 |
| 英文摘要 | Control of symmetry breaking of materials provides large opportunities to regulate their properties and functions. Herein, we report breaking the symmetry of layered dipeptide crystals by utilizing CO2 to induce the adjacent monomolecular layers to stack from the opposite to the same direction. The role of CO2 is to cover the interlayer interaction sites and force the dipeptides to adsorb at asymmetric positions. Further, the dipeptide crystals exhibit far superior piezoelectricity after symmetry breaking and the piezoelectric voltage generated from the dipeptide-based generators becomes more than 500 % higher than before. This work reveals a potential route to engineer structures and properties of layered materials and provides a deep insight into the control of non-covalent interactions. |
| 资助项目 | National Natural Science Foundation of China[22193031] ; National Natural Science Foundation of China[21961142022] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000913913200001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/56761]  |
| 通讯作者 | Li, Junbai |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci BNLMS, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xianbao,Li, Qi,Wu, Aoli,et al. CO2 Induces Symmetry Breaking in Layered Dipeptide Crystals[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022:6. |
| APA | Li, Xianbao,Li, Qi,Wu, Aoli,&Li, Junbai.(2022).CO2 Induces Symmetry Breaking in Layered Dipeptide Crystals.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,6. |
| MLA | Li, Xianbao,et al."CO2 Induces Symmetry Breaking in Layered Dipeptide Crystals".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022):6. |
入库方式： OAI收割
来源：过程工程研究所
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