In-situ fabrication of Si/FeSi2@C NPs with volume control effect by fluidized bed chemical vapor deposition as anode materials
文献类型：期刊论文
| 作者 | Du, Yu2; Hou, Guolin3; Yang, Zongxian1,6; Shi, Hebang1,6; Guo, Yafeng2; Li, Chao2; Yuan, Fangli1,4,5 |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2023-03-25 |
| 卷号 | 938页码:9 |
| ISSN号 | 0925-8388 |
| 关键词 | Si C Fluidized bed Chemical vapor deposition LIBs Alloy anodes |
| DOI | 10.1016/j.jallcom.2022.168587 |
| 英文摘要 | Silicon (Si) has been proven to be the most potential anode material for the next-generation lithium-ion batteries (LIBs) because of its superior theoretical capacity (similar to 4200 mAh g-1). However, the huge volume changes, unstable solid-state interphase (SEI) layers, and large internal stresses upon the lithiation process severely limit the practical application for commercial LIBs anodes. Herein, we fabricate the carbon-coated Si/FeSi2 nanoparticles (Si/FeSi2 @C NPs) with volume control effect by fluidized bed chemical vapor de-position (FBCVD) method to solve the above-mentioned problems. These 15 min-Si/FeSi2 @C NPs and 30 min-Si/FeSi2 @C NPs show excellent Li+ storage capacity in the first cycle (2705.9/3039.1 mAh g-1 and 2645.9/2984.2 mAh g-1) with high Initial Coulombic Efficiency (ICE) of similar to 89.0% and 88.7%. In-situ TEM characterization demonstrates that the carbon coating layer and inert FeSi2 phase enable a small volume variation, only similar to 37.8%, revealing the effective volume expansion control effect, and generating thin SEI layers. Besides, the perfect structure of Si/FeSi2 @C NPs makes this material a great improvement in rate performance.(c) 2022 Elsevier B.V. All rights reserved. |
| WOS关键词 | ION ; PERFORMANCE ; COMPOSITE ; CARBON ; NANOCOMPOSITE |
| 资助项目 | Key Program for International S T Cooperation Projects of China~from the Ministry of Science and Technology of China ; National Natural Science Foundation of China (NSFC)[11535003] ; National Natural Science Foundation of China (NSFC)[21878312] ; National Natural Science Foundation of China (NSFC)[21805282] ; National Natural Science Foundation of China (NSFC)[2019YFE0123000] ; Innovation Academy for Green Manufacture, CAS ; [11875284] ; [IAGM-2020C03] |
| WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE SA |
| WOS记录号 | WOS:000915493800001 |
| 资助机构 | Key Program for International S T Cooperation Projects of China~from the Ministry of Science and Technology of China ; National Natural Science Foundation of China (NSFC) ; Innovation Academy for Green Manufacture, CAS |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/56777]  |
| 通讯作者 | Du, Yu; Yuan, Fangli |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Zhongguancun Beiertiao 1 Hao, Beijing 100190, Peoples R China 2.SINOPEC Res Inst Safety Engn Co Ltd, State Key Lab Safety & Control Chem, Qingdao 266071, Shandong, Peoples R China 3.SINOPEC Res Inst Petr Proc, Res Ctr Renewable Energy, Coll Rd 18, Beijing 100083, Peoples R China 4.Innovat Acad Green Manufacture, Beijing 100190, Peoples R China 5.Univ Chinese Acad Sci UCAS, Ctr Mat Sci & Optoelect Engn, 19 Yuquan Rd, Beijing 100049, Peoples R China 6.Univ Chinese Acad Sci UCAS, 19 Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Yu,Hou, Guolin,Yang, Zongxian,et al. In-situ fabrication of Si/FeSi2@C NPs with volume control effect by fluidized bed chemical vapor deposition as anode materials[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2023,938:9. |
| APA | Du, Yu.,Hou, Guolin.,Yang, Zongxian.,Shi, Hebang.,Guo, Yafeng.,...&Yuan, Fangli.(2023).In-situ fabrication of Si/FeSi2@C NPs with volume control effect by fluidized bed chemical vapor deposition as anode materials.JOURNAL OF ALLOYS AND COMPOUNDS,938,9. |
| MLA | Du, Yu,et al."In-situ fabrication of Si/FeSi2@C NPs with volume control effect by fluidized bed chemical vapor deposition as anode materials".JOURNAL OF ALLOYS AND COMPOUNDS 938(2023):9. |
入库方式： OAI收割
来源：过程工程研究所
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