Separation of chitin from shrimp shells enabled by transition metal salt aqueous solution and ionic liquid
文献类型：期刊论文
| 作者 | Feng, Mi4; He, Bin4; Chen, Xinyan4; Xu, Junli2; Lu, Xingmei1,2,5; Jia, Cai2; Sun, Jian3,4 |
| 刊名 | CHINESE JOURNAL OF CHEMICAL ENGINEERING
 |
| 出版日期 | 2023 |
| 卷号 | 53页码:133-141 |
| 关键词 | Chitin Ionic liquids Transition metal salts Separation Sustainability |
| ISSN号 | 1004-9541 |
| DOI | 10.1016/j.cjche.2022.01.031 |
| 英文摘要 | Chitin is a widely used important industrial polymer mainly from shrimp shells, but its commercial preparation is under the great challenge of serious pollution due to the requirement of HCl and NaOH. Herein, we demonstrated that high purity chitin can be obtained from waste shrimp shells (WSSs) by cascade separation with transition metal salt aqueous solution and ionic liquid (IL). Firstly, calcium carbonate of WSSs was effectively removed in the metal salt aqueous solution driven by the ion exchange interaction. Subsequently, 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) had bifunctional abilities to remove residual protein and introduced metal salts simultaneously by hydrogen bonding and coordination interactions. The key experimental factors affecting the separation process were systematically studied, including the type of metal salts, temperature, and [Bmim]Cl loading. After sequential treatment with a 20% (mass) NiSO4 aqueous solution at 130 degrees C and [Bmim]Cl at 150 degrees C, the purity of a-chitin can be up to 96.5% (mass) that meets commercial requirements. The use of metal salts with higher coordination ability makes the preparation of chitin no longer depend on the commonly acid-base reaction, which is conducive to the preservation of chitin structure.(c) 2022 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights reserved. |
| WOS关键词 | DISSOLUTION ; ANTIBACTERIAL ; CELLULOSE ; CHITOSAN ; EXAMPLE ; STATE |
| 资助项目 | Startup Foundation of China[3160011181808] ; National Natural Scientific Foundation of China[21878292] ; National Natural Scientific Foundation of China[81673400] ; K. C. Wong Education Foundation[GJTD-2018-04] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000917329300001 |
| 出版者 | CHEMICAL INDUSTRY PRESS CO LTD |
| 资助机构 | Startup Foundation of China ; National Natural Scientific Foundation of China ; K. C. Wong Education Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/56806]  |
| 通讯作者 | Jia, Cai; Sun, Jian |
| 作者单位 | 1.Univ Chinese Acad Sci, Sch Chem & Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,State Key La, Beijing 100190, Peoples R China 3.Beijing Inst Technol, Minist Ind & Informat Technol, Adv Res Inst Multidisciplinary Sci, Key Lab Med Mol Sci & Pharmaceut Engn, Beijing 100081, Peoples R China 4.Beijing Inst Technol, Sch Life Sci, Key Lab Mol Med & Biotherapy, Minist Ind & Informat Technol, Beijing 100081, Peoples R China 5.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng, Mi,He, Bin,Chen, Xinyan,et al. Separation of chitin from shrimp shells enabled by transition metal salt aqueous solution and ionic liquid[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2023,53:133-141. |
| APA | Feng, Mi.,He, Bin.,Chen, Xinyan.,Xu, Junli.,Lu, Xingmei.,...&Sun, Jian.(2023).Separation of chitin from shrimp shells enabled by transition metal salt aqueous solution and ionic liquid.CHINESE JOURNAL OF CHEMICAL ENGINEERING,53,133-141. |
| MLA | Feng, Mi,et al."Separation of chitin from shrimp shells enabled by transition metal salt aqueous solution and ionic liquid".CHINESE JOURNAL OF CHEMICAL ENGINEERING 53(2023):133-141. |
入库方式： OAI收割
来源：过程工程研究所
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