A Liquid Crystal Ionomer-Type Electrolyte toward Ordering-Induced Regulation for Highly Reversible Zinc Ion Battery
文献类型：期刊论文
| 作者 | Yuan, Du2; Li, Xin2; Yao, Hong2; Li, Yuhang2; Zhu, Xiaobo2; Zhao, Jin1,5; Zhang, Haitao4; Zhang, Yizhou3; Jie, Ernest Tang Jun6; Cai, Yi6 |
| 刊名 | ADVANCED SCIENCE
 |
| 出版日期 | 2023-01-16 |
| 页码 | 10 |
| 关键词 | ionomer liquid crystal electrolyte ordering zinc ion battery Zn |
| DOI | 10.1002/advs.202206469 |
| 英文摘要 | Novel electrolyte is being pursued toward exploring Zn chemistry in zinc ion batteries. Here, a fluorine-free liquid crystal (LC) ionomer-type zinc electrolyte is presented, achieving simultaneous regulated water activity and long-range ordering of conduction channels and SEI. Distinct from water network or local ordering in current advances, long-range ordering of layered water channels is realized. Via manipulating water activity, conductivities range from approximate to 0.34 to 15 mS cm(-1), and electrochemical window can be tuned from approximate to 2.3-4.3 V. The Zn|Zn symmetric cell with LC gel exhibits highly reversible Zn stripping/plating at 5 mA cm(-2) and 5 mAh cm(-2) for 800 h, with retained ordering of water channels. The capability of gel for inducing in situ formation of long-range ordered layer SEI associated with alkylbenzene sulfonate anion is uncovered. V2O5/Zn cell with the gel shows much improved cycling stability comparing to conventional zinc electrolytes, where the preserved structure of V2O5 is associated with the efficiently stabilized Zn anode by the gel. Via long-range ordering-induced regulation on ion transport, electrochemical stability, and interfacial reaction, the development of LC electrolyte provides a pathway toward advancing aqueous rechargeable batteries. |
| WOS关键词 | LAYERED DOUBLE HYDROXIDES ; MESOMORPHIC STATE ; CHALLENGES ; WATER ; STRATEGIES ; INSIGHT ; CATHODE ; SULFATE ; DESIGN ; ANODE |
| 资助项目 | 100 Talented Team of Hunan Province[XiangZu [2016] 91] ; Natural Science Foundation of Hunan Province[2022JJ30613] ; National Natural Science Foundation of China[21878308] ; Natural Science Foundation of Jiangsu Province of China[BK20210604] ; A*STAR under the Advanced Manufacturing and Engineering (AME) programmatic fund[A20H3g2140] ; National Research Foundation of Singapore (NRF) Investigatorship Award[NRF-NRFI2017-08] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| 出版者 | WILEY |
| WOS记录号 | WOS:000914149100001 |
| 资助机构 | 100 Talented Team of Hunan Province ; Natural Science Foundation of Hunan Province ; National Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Province of China ; A*STAR under the Advanced Manufacturing and Engineering (AME) programmatic fund ; National Research Foundation of Singapore (NRF) Investigatorship Award |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/56814]  |
| 通讯作者 | Yuan, Du; Zhao, Jin; Zhang, Haitao; Srinivasan, Madhavi |
| 作者单位 | 1.Nanjing Univ Posts & Telecommun, State Key Lab Organ Elect & Informat Displays, 9 Wenyuan Rd, Nanjing 210023, Peoples R China 2.Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China 3.Nanjing Univ Informat Sci & Technol, Inst Adv Mat & Flexible Elect IAMFE, Sch Chem & Mat Sci, Nanjing 210044, Peoples R China 4.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China 5.Nanjing Univ Posts & Telecommun, Inst Adv Mat IAM, 9 Wenyuan Rd, Nanjing 210023, Peoples R China 6.Nanyang Technol Univ, Sch Mat Sci & Engn, Block N4 150 Nanyang Ave, Singapore 639798, Singapore |
| 推荐引用方式 GB/T 7714 | Yuan, Du,Li, Xin,Yao, Hong,et al. A Liquid Crystal Ionomer-Type Electrolyte toward Ordering-Induced Regulation for Highly Reversible Zinc Ion Battery[J]. ADVANCED SCIENCE,2023:10. |
| APA | Yuan, Du.,Li, Xin.,Yao, Hong.,Li, Yuhang.,Zhu, Xiaobo.,...&Srinivasan, Madhavi.(2023).A Liquid Crystal Ionomer-Type Electrolyte toward Ordering-Induced Regulation for Highly Reversible Zinc Ion Battery.ADVANCED SCIENCE,10. |
| MLA | Yuan, Du,et al."A Liquid Crystal Ionomer-Type Electrolyte toward Ordering-Induced Regulation for Highly Reversible Zinc Ion Battery".ADVANCED SCIENCE (2023):10. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。