Scalable Palladium-Catalyzed Alkoxycarbonylation of Conjugated Dienes
文献类型：期刊论文
| 作者 | Zhang, Zi-Heng1,2; Han, Li-Jun1,3; Ma, Shuang-Shuang1,3; Du, Yi-Ran4; Yu, Zheng-Kun3; Lin, Jin-Qing2; Xu, Bao-Hua1,3,4 |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2023-01-05 |
| 页码 | 11 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/acs.joc.2c02245 |
| 英文摘要 | The Pd(cod)Cl2-catalyzed alkoxycarbonylation of conjugated dienes to beta,gamma-unsaturated esters was approached by both intramolecular phosphinesulfonate L1 and intermolecular PPh3/PTSA in this study. However, the poor solubility of the Pd/ L1 complex and the labile monodentate Pd/PPh3 structure restricts the system efficiency, especially for the scale-up application. By contrast, the stable and well-soluble bidentate Xantphos system allows for the quantitative formation of 3-pentenoate (96%) on a gram scale within 6 h in weakly alkaline N-methylpyrrolidone (NMP), which also functions as a basic site to promote the rate-limiting alcoholysis step while reducing the dosage of ligand to a theoretical value. |
| WOS关键词 | ADIPIC ACID ; 1,3-BUTADIENE |
| 资助项目 | National Natural Science Foundation of China Youth Fund[22022815] ; National Natural Science Foundation of China[22208015] ; National Natural Science Foundation of China[22078336] ; Innovation Academy for Green Manufacture, CAS[IAGM2020C13] ; National Science Foundation of Fujian Province[2020J01065] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000912941500001 |
| 资助机构 | National Natural Science Foundation of China Youth Fund ; National Natural Science Foundation of China ; Innovation Academy for Green Manufacture, CAS ; National Science Foundation of Fujian Province |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/56855]  |
| 通讯作者 | Lin, Jin-Qing; Xu, Bao-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Huaqiao Univ, Coll Mat Sci & Engn, Xiamen 361021, Peoples R China 3.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China 4.Beijing Inst Technol, Sch Chem & Chem Engn, Beijing Key Lab Chem Power Source & Green Catalysi, Beijing 100081, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zi-Heng,Han, Li-Jun,Ma, Shuang-Shuang,et al. Scalable Palladium-Catalyzed Alkoxycarbonylation of Conjugated Dienes[J]. JOURNAL OF ORGANIC CHEMISTRY,2023:11. |
| APA | Zhang, Zi-Heng.,Han, Li-Jun.,Ma, Shuang-Shuang.,Du, Yi-Ran.,Yu, Zheng-Kun.,...&Xu, Bao-Hua.(2023).Scalable Palladium-Catalyzed Alkoxycarbonylation of Conjugated Dienes.JOURNAL OF ORGANIC CHEMISTRY,11. |
| MLA | Zhang, Zi-Heng,et al."Scalable Palladium-Catalyzed Alkoxycarbonylation of Conjugated Dienes".JOURNAL OF ORGANIC CHEMISTRY (2023):11. |
入库方式： OAI收割
来源：过程工程研究所
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