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Facile synthesis of N-rich carbon nanosheets derived from antibiotic mycelial dregs as efficient catalysts for peroxymonosulfate activation

文献类型：期刊论文

作者Hao, Rongjiang1,3,4; Du, Lin1; Gu, Xiangyu1; Li, Songgeng1,2,3
刊名SEPARATION AND PURIFICATION TECHNOLOGY
出版日期2023-02-01
卷号306页码:15
关键词Carbon catalyst Penicillin mycelial dregs Molten salt-assisted pyrolysis Advanced oxidation processes
ISSN号1383-5866
DOI10.1016/j.seppur.2022.122571
英文摘要Nitrogen-rich carbon nanosheets using hazardous waste penicillin mycelial dregs (PMD) as the sole precursor were successfully synthesized amid molten salt-assisted pyrolysis and applied as catalysts for peroxymonosulfate (PMS) activation to degrade acid orange 7 (AO7). The structural properties and the associated catalytic per-formances of carbon nanosheets were precisely regulated by molten salt (NaCl/KCl) mass ratios and pyrolysis temperatures. Carbon nanosheets prepared at a molten salt ratio of 6 and a pyrolysis temperature of 800 degrees C possessed an optimized catalytic performance, achieving both high effective and efficient decolorization of AO7 than activated carbon catalysts. It was likely attributed to the combination of high graphitic N content and defective carbon structures from nanosheets through quantitative structure-activity relationships analysis. Both radical and non-radical pathways were recognized to be responsible for AO7 degradation, while surface-bound radicals generated from catalyst surface-PMS complexes in non-radical pathways were the main reactive oxygen species. This work offers a green and facile method to prepare high graphitic N content and defect-rich carbon nanosheets from nitrogen-rich biowastes, highlighting its promising catalytic properties for environmental remediation, synchronously expanding the means of resourceful and harmless treatment of PMD to improve the sustainability of antibiotic pharmaceutical production.
WOS关键词REDUCED GRAPHENE OXIDE ; POROUS CARBON ; AZO-DYE ; DEGRADATION ; OXIDATION ; PERFORMANCE ; ADSORPTION ; BIOMASS ; DECOLORIZATION ; PHOTOOXIDATION
资助项目National Key R & D Pro- gram of China ; [2018YFC1901300]
WOS研究方向Engineering
语种英语
WOS记录号WOS:000916005100002
出版者ELSEVIER
资助机构National Key R & D Pro- gram of China
源URL[http://ir.ipe.ac.cn/handle/122111/56877]  
通讯作者Li, Songgeng
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
3.Univ Chinese Acad Sci, Sino Danish Coll, Beijing 100049, Peoples R China
4.Sino Danish Ctr Educ & Res, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714		 Hao, Rongjiang,Du, Lin,Gu, Xiangyu,et al. Facile synthesis of N-rich carbon nanosheets derived from antibiotic mycelial dregs as efficient catalysts for peroxymonosulfate activation[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2023,306:15.
APA Hao, Rongjiang,Du, Lin,Gu, Xiangyu,&Li, Songgeng.(2023).Facile synthesis of N-rich carbon nanosheets derived from antibiotic mycelial dregs as efficient catalysts for peroxymonosulfate activation.SEPARATION AND PURIFICATION TECHNOLOGY,306,15.
MLA Hao, Rongjiang,et al."Facile synthesis of N-rich carbon nanosheets derived from antibiotic mycelial dregs as efficient catalysts for peroxymonosulfate activation".SEPARATION AND PURIFICATION TECHNOLOGY 306(2023):15.

入库方式： OAI收割

来源：过程工程研究所

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