Sc(OTf)3-catalyzed synthesis of indoles and SnCl4-mediated regioselective hydrochlorination of 5-(arylamino)pent-3-yn-2-ones
文献类型：期刊论文
| 作者 | Yang F(杨芳) ; Ji KG(纪克攻) ; Ali Shaukat ; Liang YM(梁永民) |
| 刊名 | J.Org.Chem
 |
| 出版日期 | 2011 |
| 卷号 | 76页码:8329-8335 |
| ISSN号 | 0022-3263 |
| 通讯作者 | 梁永民 |
| 中文摘要 | Highly substituted indole derivatives bearing alkyl and aryl moieties can be prepared by Sc(OTf)3-catalyzed Friedel Crafts alkenylation of 5-(arylamino)pent-3-yn-2-ones. In addition, a method for regioselective hydrochlorination of 5-(arylamino)pent-3- yn-2-onesmediated by SnCl4 inmoderate to good yields (up to 84%) has been developed. The resulting exclusive Z-selectivity of the C Cl bond can be further exploited using cross C N coupling reactions. |
| 学科主题 | 材料科学与物理化学 |
| 收录类别 | SCI |
| 资助信息 | the NSF (NSF-21072080;NSF-20732002);the National Basic Research Program of China (973 program),2010CB833203 |
| 语种 | 英语 |
| 公开日期 | 2013-10-15 |
| 源URL | [http://210.77.64.217/handle/362003/3964]  |
| 专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Yang F,Ji KG,Ali Shaukat,et al. Sc(OTf)3-catalyzed synthesis of indoles and SnCl4-mediated regioselective hydrochlorination of 5-(arylamino)pent-3-yn-2-ones[J]. J.Org.Chem,2011,76:8329-8335. |
| APA | 杨芳,纪克攻,Ali Shaukat,&梁永民.(2011).Sc(OTf)3-catalyzed synthesis of indoles and SnCl4-mediated regioselective hydrochlorination of 5-(arylamino)pent-3-yn-2-ones.J.Org.Chem,76,8329-8335. |
| MLA | 杨芳,et al."Sc(OTf)3-catalyzed synthesis of indoles and SnCl4-mediated regioselective hydrochlorination of 5-(arylamino)pent-3-yn-2-ones".J.Org.Chem 76(2011):8329-8335. |
入库方式： OAI收割
来源：兰州化学物理研究所
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