Excess spectroscopy and its applications in the study of solution chemistry
文献类型：会议论文
| 作者 | Zhang, Yaqin1; Wu, Zhiwei1; Wang, Yaqian2; He, Hongyan1; Yu, Zhiwu2 |
| 出版日期 | 2020-10-01 |
| 关键词 | Molecular spectroscopy - Ionic liquids |
| 卷号 | 92 |
| 期号 | 10 |
| DOI | 10.1515/pac-2020-0107 |
| 页码 | 1611-1626 |
| 英文摘要 | Characterization of structural heterogeneity of liquid solutions and the pursuit of its nature have been challenging tasks to solution chemists. In the last decade, an emerging method called excess spectroscopy has found applications in this area. The method, combining the merits of molecular spectroscopy and excess thermodynamic functions, shows the ability to enhance the apparent resolution of spectra, provides abundant information concerning solution structures and intermolecular interactions. In this review, the thinking and mathematics of the method, as well as its developments, are presented first. Then, research progress related to the exploration of the method is thoroughly reviewed. The materials are classified into two parts, small-molecular solutions and ionic liquid solutions. Finally, potential challenges and the perspective for further development of the method are discussed. 漏 2020 IUPAC & De Gruyter. |
| 项目编号 | This work was supported by the National Science Fund for Excellent Young Scholars (21922813), National Natural Science Foundation of China (21733011, 21834006), and Youth Innovation Promotion Association of CAS (2017066). |
| 资助机构 | De Gruyter Open Ltd |
| 学科主题 | Hydrogen Bonds |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/59278]  |
| 作者单位 | 1.CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex Systems, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing; 100190, China 2.MOE Key Laboratory of Bioorganic Phosphorous Chemistry and Chemical Biology, Department of Chemistry, Tsinghua University, Beijing; 100084, China |
| 推荐引用方式 GB/T 7714 | Zhang, Yaqin,Wu, Zhiwei,Wang, Yaqian,et al. Excess spectroscopy and its applications in the study of solution chemistry[C]. 见:. |
入库方式： OAI收割
来源：过程工程研究所
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