Single-step conversion of cellobiose to 5-Hydroxymethylfurfural(5-HMF) catalyzed by poly ionic liquid
文献类型：会议论文
| 作者 | Song, Yan Lei2; Qu, Yongs Hui1; Huang, Chong Pin2; Ge, Li Hai2; Li, Ying Xia2; Chen, Biao Hua2 |
| 出版日期 | 1905-07-06 |
| 会议日期 | June 14, 2014 - June 15, 2014 |
| 会议地点 | Xiamen, China |
| 关键词 | Ionic liquids - Glucose |
| 卷号 | 1004-1005 |
| DOI | 10.4028/www.scientific.net/AMR.1004-1005.885 |
| 页码 | 885-890 |
| 英文摘要 | The PIL which were prepared from imidazole and epichlorohydrin were used as catalysts for the conversion of cellobiose to 5-HMF. Effects of the catalyst anion, solvents, reaction temperature, and recycling time were investigated in detail. The optimum reaction conditions for conversion of cellobiose into 5-HMFcatalysed by [IMEP]BF4 were temperature 180 掳C, cellobiose 0.5 g, and [IMEP]BF4 0.25 g in DMSO(30 mL). In this condition the yield of 5-HMF can reach 39.2% for 420min. The good positive correlation between the concentration of glucose and the formation rate of 5-HMF was given, and the conversion of glucose into 5-HMF is the key step of formation of 5-HMF from cellobiose. Moreover, [IMEP]BF4 has well cycle performance in the optimum reaction condition. 漏 (2014) Trans Tech Publications, Switzerland. |
| 资助机构 | Trans Tech Publications Ltd |
| 会议录 | 4th International Conference on Advanced Engineering Materials and Technology, AEMT 2014
 |
| 学科主题 | Catalysts |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/59386]  |
| 作者单位 | 1.National Key Laboratory of Biochemical Engineering, Institute of process Engineering, Chinese Academy of Sciences, Beijing 100190, China 2.State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Postbox 35, Beijing 100029, China |
| 推荐引用方式 GB/T 7714 | Song, Yan Lei,Qu, Yongs Hui,Huang, Chong Pin,et al. Single-step conversion of cellobiose to 5-Hydroxymethylfurfural(5-HMF) catalyzed by poly ionic liquid[C]. 见:. Xiamen, China. June 14, 2014 - June 15, 2014. |
入库方式： OAI收割
来源：过程工程研究所
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