Resin material used in methyl acrylate hydrolysis reaction
文献类型：会议论文
| 作者 | Li, Ya-Ping1,2; Huo, Quan1; Zuo, Cun-Cun2; Cao, Sha-Sha2; Wang, Er-Qiang3 |
| 出版日期 | 1905-07-06 |
| 会议日期 | August 8, 2014 - August 9, 2014 |
| 会议地点 | Xi'an, Shanxi, China |
| 关键词 | Hydrolysis - Ion exchange - Ion exchange resins - Positive ions - Carboxylic acids - Catalysts - Activation energy - Reusability |
| 卷号 | 1035 |
| DOI | 10.4028/www.scientific.net/AMR.1035.307 |
| 页码 | 307-312 |
| 英文摘要 | In this work, the ion exchange resin catalyst named D072 were used in the hydrolysis of a methyl acrylate to acrylic acid and methanol firstlyand chemical equilibrium would be achieved during the process of the reversible reaction system. The influences of parameters such as dosage of catalyst, initial reactants molar ratio and reaction temperature were investigated. Meanwhile, the reusability of cation-exchange resin was studied, and no phenomenon of deactivation was found with using of reused catalyst. Moreover, the experimental data were analyzed by the pseudo-homogeneous (PH) model and the hydrolysis dynamics equation of methyl acrylate was obtained and found that the activation energy of the reaction was 118.37 KJ/mol in the presence of D072. Based on the result, high energy would be needed to the hydrolysis of methyl acrylate in using D072 resin as catalyst. 漏 (2014) Trans Tech Publications, Switzerland. |
| 资助机构 | Trans Tech Publications Ltd |
| 会议录 | 2014 International Conference on Material Science and Engineering, ICMSE2014
 |
| 学科主题 | Reaction Kinetics |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/59453]  |
| 作者单位 | 1.College of Environmental and Chemical Engineering, Hebei Key Laboratory of Applied Chemistry, Yanshan University, Qinhuangdao; Hebei Province, China 2.Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China 3.College of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, China |
| 推荐引用方式 GB/T 7714 | Li, Ya-Ping,Huo, Quan,Zuo, Cun-Cun,et al. Resin material used in methyl acrylate hydrolysis reaction[C]. 见:. Xi'an, Shanxi, China. August 8, 2014 - August 9, 2014. |
入库方式： OAI收割
来源：过程工程研究所
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