中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Production TiCl4 using combined fluidized bed by titanium slag containing high-level CaO and MgO

文献类型:会议论文

作者Yuan, Zhangfu1; Pan, Yifang2; Xu, Cong1; Li, Jing1
出版日期1905-06-27
会议日期September 25, 2005 - September 28, 2005
会议地点Pittsburgh, PA, United states
关键词Agglomeration - Fluidized beds - Lime - Magnesia - Slags - Titanium compounds
卷号3
页码27-38
英文摘要This paper describes a new method for producing TiCl4 by chloridizing materials of high-level CaO and MgO, in which a combined fluidized bed is used as a reactor to avoid agglomeration between particles caused by molten CaCl2 and MgCl2. The combined fluidized bed consists of at least a riser tube and a semi-circulating fluidized bed. Two kinds of high titanium slag, in which the total content of CaO and MgO is 2.03 wt% and 9.09 wt% respectively, are employed to examine the anti-agglomeration effect and the conversion of the materials when the temperature ranges are between 923.15K and 1073.15K, gas apparent velocity 0.7-1.1m/s, and inlet amount of solid materials is 4.6kg/h-7.0kg/h. It is found that the anti-agglomeration effect in the combined fluidized bed is satisfactory and the new method can achieve a production capacity of 14.0-75.4 t-TiCl4·m -2·d-1 in relation to 25.0-40.0 t-TiCl 4-m-2·d-1 from the conventional bubble bed. Furthermore, low-temperature chloridization, for example, at 923K or 973 K, can also be used to produce TiCl4 and avoid agglomeration.
项目编号This work was supported by National Natural Science Foundation (No. 20306030) of China.
资助机构Association for Iron and Steel Technology, AISTECH
会议录Materials Science and Technology 2005 Conference
学科主题Synthesis (Chemical)
源URL[http://ir.ipe.ac.cn/handle/122111/59584]  
作者单位1.Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080, China
2.Tianjin Iron and Steel Co. Ltd., Tianjin 300301, China
推荐引用方式
GB/T 7714
Yuan, Zhangfu,Pan, Yifang,Xu, Cong,et al. Production TiCl4 using combined fluidized bed by titanium slag containing high-level CaO and MgO[C]. 见:. Pittsburgh, PA, United states. September 25, 2005 - September 28, 2005.

入库方式: OAI收割

来源:过程工程研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。