Production TiCl4 using combined fluidized bed by titanium slag containing high-level CaO and MgO
文献类型:会议论文
作者 | Yuan, Zhangfu1; Pan, Yifang2; Xu, Cong1; Li, Jing1 |
出版日期 | 1905-06-27 |
会议日期 | September 25, 2005 - September 28, 2005 |
会议地点 | Pittsburgh, PA, United states |
关键词 | Agglomeration - Fluidized beds - Lime - Magnesia - Slags - Titanium compounds |
卷号 | 3 |
页码 | 27-38 |
英文摘要 | This paper describes a new method for producing TiCl4 by chloridizing materials of high-level CaO and MgO, in which a combined fluidized bed is used as a reactor to avoid agglomeration between particles caused by molten CaCl2 and MgCl2. The combined fluidized bed consists of at least a riser tube and a semi-circulating fluidized bed. Two kinds of high titanium slag, in which the total content of CaO and MgO is 2.03 wt% and 9.09 wt% respectively, are employed to examine the anti-agglomeration effect and the conversion of the materials when the temperature ranges are between 923.15K and 1073.15K, gas apparent velocity 0.7-1.1m/s, and inlet amount of solid materials is 4.6kg/h-7.0kg/h. It is found that the anti-agglomeration effect in the combined fluidized bed is satisfactory and the new method can achieve a production capacity of 14.0-75.4 t-TiCl4·m -2·d-1 in relation to 25.0-40.0 t-TiCl 4-m-2·d-1 from the conventional bubble bed. Furthermore, low-temperature chloridization, for example, at 923K or 973 K, can also be used to produce TiCl4 and avoid agglomeration. |
项目编号 | This work was supported by National Natural Science Foundation (No. 20306030) of China. |
资助机构 | Association for Iron and Steel Technology, AISTECH |
会议录 | Materials Science and Technology 2005 Conference
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学科主题 | Synthesis (Chemical) |
源URL | [http://ir.ipe.ac.cn/handle/122111/59584] ![]() |
作者单位 | 1.Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080, China 2.Tianjin Iron and Steel Co. Ltd., Tianjin 300301, China |
推荐引用方式 GB/T 7714 | Yuan, Zhangfu,Pan, Yifang,Xu, Cong,et al. Production TiCl4 using combined fluidized bed by titanium slag containing high-level CaO and MgO[C]. 见:. Pittsburgh, PA, United states. September 25, 2005 - September 28, 2005. |
入库方式: OAI收割
来源:过程工程研究所
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