Effect of CoCl2 catalyst on pyrolysis of lignite
文献类型：会议论文
| 作者 | Zou, Xianwu1,2; Qin, Tefu1; Yao, Jianzhong2; Yang, Xuemin2; Song, Wenli2; Lin, Weigang2 |
| 出版日期 | 1905-06-29 |
| 会议日期 | September 10, 2007 - September 14, 2007 |
| 会议地点 | Johannesburg, South africa |
| 关键词 | Tar - Cobalt compounds - Pyrolysis - Catalysts - Thermogravimetric analysis - Phenols - Recycling - Lignite - Zeolites |
| 卷号 | 3 |
| 页码 | 1223-1237 |
| 英文摘要 | Coal pyrolysis can be significantly affected by CoCl2 catalyst. In this paper, the effect of CoCl2 catalyst on the pyrolysis of Huolinhe lignite was investigated in a spout-entrainment reactor and in a thermogravimetric cell. The results showed that the yield of total volatile from lignite fast pyrolysis using CoCl2 catalyst was twice as much as that without CoCl2 catalyst. Moreover, the main components of light tar, including phenol, carboxylic and aliphatic groups were also increased by 150 %, 83 %, 100 % and 200 %, respectively. On the contrary, the slow pyrolysis of lignite was inhibited by CoCl2 catalyst: the yield of total volatile and the yields of phenol and carboxylic groups were all decreased. The different effect of CoCl2 catalyst on fast and slow pyrolysis of coal might be attributed to secondary cracking of tar precursors. In order to recycle Co catalyst, CoCl2 was impregnated to clay zeolite. The catalytic effect of Co-clay zeolite is lower than that of CoCl2 directly impregnated to lignite. However, catalytic pyrolysis of lignite with Co-clay zeolite should be feasible in an industrial setting because it's easy to be separated and recycled. |
| 资助机构 | International Pittsburgh Coal Conference |
| 会议录 | 24th Annual International Pittsburgh Coal Conference 2007, PCC 2007
 |
| 学科主题 | Chlorine Compounds |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/59589]  |
| 作者单位 | 1.Research Institute of Wood Industry, Key Laboratory of Wood Science and Technology of SFA, Chinese Academy of Forestry, Beijing 100091, China 2.State Key Laboratory of Multi-phase Complex System, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080, China |
| 推荐引用方式 GB/T 7714 | Zou, Xianwu,Qin, Tefu,Yao, Jianzhong,et al. Effect of CoCl2 catalyst on pyrolysis of lignite[C]. 见:. Johannesburg, South africa. September 10, 2007 - September 14, 2007. |
入库方式： OAI收割
来源：过程工程研究所
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