Variation Laws of Heat Storage Performances and Heat Storage Stability of ZrO2 Electrolyte Materials with Temperature and Time
文献类型:会议论文
作者 | Zeng, Chong1; Zhou, Dengmei1; Xiang, Jing1; Zheng, Ruilun1; Tian, Liangliang1; Li, Peng1; Song, Jing2 |
出版日期 | 1905-07-14 |
会议日期 | July 29, 2022 - July 31, 2022 |
关键词 | Atoms - Ceramic materials - Heat storage - Oxygen sensors - Solid electrolytes - Stability - Storage (materials) - Zirconia |
卷号 | 12451 |
DOI | 10.1117/12.2656597 |
英文摘要 | ZrO2 electrolyte is one of key parts of solid electrolyte oxygen sensors. The heat storage performances and heat storage stability of ZrO2 electrolyte influence the performance of solid electrolyte oxygen sensors directly. Sensors work in high-temperature changing environment and the prominent non-harmonic effect of atomic vibration of ZrO2 electrolyte materials can influence heat storage performances and heat storage stability of sensor significantly. To improve performances and thermostability of electrolyte, non-harmonic vibration of atoms were taken into account in this study. The variation laws of heat capacity and heat storage stability of ZrO2 electrolyte materials with temperature and time were investigated by solid physical theories and methods. Moreover, influences of non-harmonic vibration of atoms were discussed. Results demonstrate that the Debye temperature achieves a linear growth as temperature rises due to the non-harmonic effect. The constant-volume specific heat presents a nonlinear growth as temperature rises and it shows an approximate negative exponential attenuation as time goes on. The constant-volume specific heat decreases due to the non-harmonic effect. The reduction amplitude increases firstly and then decreases with time, but it increases gradually as time goes on. Heat storage stability weakens firstly and then enhances with the increase of temperature and it is poorest at about 160K. Heat storage stability is weakened to a small extent due to the non-harmonic effect. The results are basically consistent with other literature results. Research conclusions can provide theoretical references to study stability and service life of solid electrolyte oxygen sensors. 漏 2022 SPIE. |
项目编号 | The work is financially Supported by the Science and Technology Research Program of Chongqing Municipal Education Commission (Grant No. HZ2021013, KJQN202101317 and KJQN202101306), Foundation of Chongqing University of Arts and Sciences (Grant No. R2020SDQ02 and R2019FDQ13), the Natural Science Foundation of Chongqing (Grant No. cstc2019jcyj-msxmX0474) and Chongqing Human Resources and Social Security Bureau (Grant No.2021XM3068). |
会议录 | Proceedings of SPIE - The International Society for Optical Engineering
![]() ![]() |
会议录出版者 | SPIE |
学科主题 | Specific Heat |
源URL | [http://ir.ipe.ac.cn/handle/122111/59621] ![]() |
作者单位 | 1.School of Electronic Information and Electrical Engineering, Chongqing University of Arts and Sciences, Chongqing; 402160, China 2.National Engineering Research Center of Green Recycling for Strategic Metal Resources, Institute of Process Engineering, Chinese Academy of Sciences, Beijing; 100190, China |
推荐引用方式 GB/T 7714 | Zeng, Chong,Zhou, Dengmei,Xiang, Jing,et al. Variation Laws of Heat Storage Performances and Heat Storage Stability of ZrO2 Electrolyte Materials with Temperature and Time[C]. 见:. July 29, 2022 - July 31, 2022. |
入库方式: OAI收割
来源:过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。