A novel catalyst prepared from black liquor for biodiesel conversion: An optimization study
文献类型:会议论文
作者 | Sun, Y.2; Liu, J.Z.2; He, H.Z.2; Wang, Y.X.2; Yang, G.1; Liu, Y.Y.3; He, J.2; Xiao, X.1 |
出版日期 | 2021-01-27 |
会议日期 | November 1, 2020 - November 4, 2020 |
关键词 | Catalysts - Transesterification - Carbonization - Methanol - Loading |
卷号 | 1765 |
期号 | 1 |
DOI | 10.1088/1742-6596/1765/1/012011 |
英文摘要 | This paper reports a new approach for high-value conversion of black liquor into biochar to catalyse the transesterification for biodiesel conversion using waste fry oil (WFO). The central composite design (CCD) and response surface methodology (RSM) were employed to optimize the biodiesel preparation using the catalyst prepared from the paper pulp black liquor precipitated biochar. The transesterification reaction is catalysed by oxidative functional groups (enolic) on the surface of biochar. The effect of alkaline loading in biochar, carbonization temperature, the methanol to oil ratio and the catalyst loading were systematically investigated. The optimal biodiesel conversion conditions were achieved as the following: 27wt% (alkaline loading in biochar), 585 掳C (carbonization temperature), 7 (methanol to oil ratio) and 5.5 wt% (catalyst loading), with the biodiesel yield of 95%. 漏 Published under licence by IOP Publishing Ltd. |
项目编号 | The authors would like to appreciate the funding support of the following: National Key R&D Program of China (2018YFC1903500), FIG grant from Faculty Inspiration Grant UNNC (2019FIG), Qianjiang Talent Scheme-(QJD1803014), Conference grant from Faculty of Science and Engineering of UNNC. |
会议录 | Journal of Physics: Conference Series ; 2nd International Conference on Graphene and Novel Nanomaterials, GNN 2020 |
会议录出版者 | IOP Publishing Ltd |
学科主题 | Biodiesel |
源URL | [http://ir.ipe.ac.cn/handle/122111/59639] |
作者单位 | 1.National Engineering Laboratory of Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing; 100190, China 2.Department of Chemical and Environmental Engineering, University of Nottingham Ningbo China, 199 Taikang E Rd, Ningbo, Zhejiang; 315100, China 3.University College London (UCL), Department of Chemical Engineering, 20 Gordon Street, London; WC1E 7JE, United Kingdom |
推荐引用方式 GB/T 7714 | Sun, Y.,Liu, J.Z.,He, H.Z.,et al. A novel catalyst prepared from black liquor for biodiesel conversion: An optimization study[C]. 见:. November 1, 2020 - November 4, 2020. |
入库方式: OAI收割
来源:过程工程研究所
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