The exploration of metal-free catalyst g-C3N4 for NO degradation
文献类型：期刊论文
| 作者 | Ren, Yuehong1,2; Han, Qingzhen2; Zhao, Yuehong2; Wen, Hao2; Jiang, Zhaotan1 |
| 刊名 | Journal of Hazardous Materials
 |
| 出版日期 | 2021-02-15 |
| 卷号 | 404 |
| 关键词 | Catalysts - Molecules - Reaction intermediates |
| ISSN号 | 3043894 |
| DOI | 10.1016/j.jhazmat.2020.124153 |
| 英文摘要 | We propose a new metal-free scheme of the reaction between the molecules CO and NO on a g-C3N4 monolayer. We first investigate the electronic properties of the related molecules CO, NO, N2, and CO2 adsorbed g-C3N4 systems, and then figure out the possible reaction pathways. It is shown that all the molecules will be physisorbed above the triangular cavity. Also, we find the NO binding on g-C3N4 is stronger than CO. The NO dissociation will be the rate-determining step of the reaction, and the formation of NCO路 intermediate will play a critical role for the reaction process. This research presents a new route of applying g-C3N4 as a catalyst in the NO catalytic degradation reaction. 漏 2020 Elsevier B.V. |
| 学科主题 | Electronic Properties |
| 项目编号 | This work was supported by the National Key Research and Development Program of China (Grant No. 2017YFC0210304 ) ; the National Natural Science Foundation of China (Grant No. 11774029 ) ; the CAS Informatization Program of the Thirteenth Five-Year Plan (No. XXH1350303&ndash ; 103 ) ; and the National Water Pollution Control, Control Scientific and Technological Special Project (Grant No. 2017ZX07402001 ).This work was supported by the National Key Research and Development Program of China (Grant No. 2017YFC0210304) ; the National Natural Science Foundation of China (Grant No. 11774029) ; the CAS Informatization Program of the Thirteenth Five-Year Plan (No. XXH1350303?103) ; and the National Water Pollution Control, Control Scientific and Technological Special Project (Grant No. 2017ZX07402001). |
| 出版者 | Elsevier B.V., Netherlands |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/60276]  |
| 作者单位 | 1.School of Physics, Beijing Institute of Technology, Beijing; 100081, China 2.State Key Laboratory of Multiphase Complex System, Beijing Engineering Research Centre of Process Pollution Control, Institute of Process Engineering, Chinese Academy of Sciences, Beijing; 100190, China |
| 推荐引用方式 GB/T 7714 | Ren, Yuehong,Han, Qingzhen,Zhao, Yuehong,et al. The exploration of metal-free catalyst g-C3N4 for NO degradation[J]. Journal of Hazardous Materials,2021,404. |
| APA | Ren, Yuehong,Han, Qingzhen,Zhao, Yuehong,Wen, Hao,&Jiang, Zhaotan.(2021).The exploration of metal-free catalyst g-C3N4 for NO degradation.Journal of Hazardous Materials,404. |
| MLA | Ren, Yuehong,et al."The exploration of metal-free catalyst g-C3N4 for NO degradation".Journal of Hazardous Materials 404(2021). |
入库方式： OAI收割
来源：过程工程研究所
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