Investigation of MOF-derived humidity-proof hierarchical porous carbon frameworks as highly-selective toluene absorbents and sensing materials
文献类型：期刊论文
| 作者 | Li, Zehui4; Yuan, Yi4; Wu, Hao2; Li, Xinghui2; Yuan, Menglei1; Wang, Huaizhang3; Wu, Xiaoxue4; Liu, Shuai4; Zheng, Xianming4; Kim, Mingjun4 |
| 刊名 | Journal of Hazardous Materials
 |
| 出版日期 | 2021-06-05 |
| 卷号 | 411 |
| 关键词 | Carbon - Organic carbon - Toluene - Crystals - Metal-Organic Frameworks - Adsorption - Quartz crystal microbalances - Crystalline materials - Quartz - Carbonization - Porous materials |
| ISSN号 | 3043894 |
| DOI | 10.1016/j.jhazmat.2020.125034 |
| 英文摘要 | Carbon frameworks (CFs) derived from metal-organic frameworks (MOFs) have been produced as adsorbents of toluene. To further obtain optimum hierarchical porous carbon structure of CFs, different treatment temperatures were applied to a typical kind of MOFs (ZIF-8). The adsorption capacity of the toluene of hierarchical porous CFs obtained from ZIF-8 under 1100 掳C (CF-1100, adsorption capacity of 208.5 mg/g) was higher than that of other carbonization temperature and MOFs. Impressively, the adsorbent CF-1100 also exhibited strong hydrophobicity, low desorption temperature, and good selectivity to toluene. The adsorption capacity decreased by only 10.4% under wet condition compared with the dry condition, standing on the top of the recently reported adsorbents. The impressive adsorption performance of CF-1100 is attributed to the larger specific surface area (1024 m2/g) and pore volume (0.497 cm3/g), newly generated micropores (pore width is 0.6鈥?.8 nm) and mesopores (pore width above 10 nm), and carbonaceous structure with higher degree of graphitization. Based on the adequate adsorption performance, CF-1100 coated quartz crystal microbalances as sensor also showed a high sensitivity of 0.4004 Hz/ppm and small relative standard deviations of 1.0745% for toluene sensing. This contribution provides a foundation for optimizing potential adsorbents and sensing materials for air pollution abatement. 漏 2021 Elsevier B.V. |
| 学科主题 | Volatile Organic Compounds |
| 项目编号 | Financial support from the National Key Research and Development Plan Project of China ( 2016YFC0200102 ) is acknowledged. |
| 出版者 | Elsevier B.V. |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/60346]  |
| 作者单位 | 1.Beijing Engineering Research Center of Process Pollution Control, Institute of Process Engineering, Chinese Academy of Sciences, Beijing; 100049, China 2.Division of Advanced Manufacturing, Graduate School at Shenzhen, Tsinghua University, Shenzhen; 518055, China 3.Key Laboratory of Advanced Materials (MOE), School of Materials Science and Engineering, Tsinghua University, Beijing; 100084, China 4.State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing; 100084, China |
| 推荐引用方式 GB/T 7714 | Li, Zehui,Yuan, Yi,Wu, Hao,et al. Investigation of MOF-derived humidity-proof hierarchical porous carbon frameworks as highly-selective toluene absorbents and sensing materials[J]. Journal of Hazardous Materials,2021,411. |
| APA | Li, Zehui.,Yuan, Yi.,Wu, Hao.,Li, Xinghui.,Yuan, Menglei.,...&Jiang, Jingkun.(2021).Investigation of MOF-derived humidity-proof hierarchical porous carbon frameworks as highly-selective toluene absorbents and sensing materials.Journal of Hazardous Materials,411. |
| MLA | Li, Zehui,et al."Investigation of MOF-derived humidity-proof hierarchical porous carbon frameworks as highly-selective toluene absorbents and sensing materials".Journal of Hazardous Materials 411(2021). |
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来源：过程工程研究所
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