From fundamentals to chemical engineering on oxidative coupling of methane for ethylene production: A review
文献类型：期刊论文
| 作者 | Liu, Jiao1; Yue, Junrong1; Lv, Mei1,3; Wang, Fang2; Cui, Yanbin1; Zhang, Zhanguo3; Xu, Guangwen1,3 |
| 刊名 | Carbon Resources Conversion
 |
| 出版日期 | 2022-03-01 |
| 卷号 | 5期号:1页码:44940 |
| 关键词 | Temperature - Reaction intermediates - Reaction kinetics - Catalyst selectivity - Methane - Chemical reactors |
| DOI | 10.1016/j.crcon.2021.11.001 |
| 英文摘要 | A comprehensive overview is presented to summarize the research works since 1982 on oxidative coupling of methane (OCM), a complex reaction network combining heterogeneous and homogeneous reaction steps. Fundamentals on reaction mechanisms and thermodynamics have revealed that the OCM process is highly exothermic and its C2+ selectivity and yield is critical in evaluating its commercial viability. Catalytic strategies have been put to enhance C2+ selectivity, improve C2+ yield and lower reaction temperature. The catalyst Mn-Na2WO4/SiO2 enables methane activation at a temperature of 800 掳C and simultaneously a high C2+ selectivity of 70鈥?0%, while the nanowire and La2O3-based catalysts enable to lower the reaction temperature to 200鈥?00 掳C and 500 掳C, respectively. Reaction engineering aspects have also been dealt in many investigations in order to make the process technically feasible. Particularly, research works on reaction kinetics, reactor selection and reactor operating mode choice have been addressed. Intermediate cooling and distributed oxygen feed have been integrated into a multi-stage adiabatic fixed-bed reactor system to suppress the side oxidation reactions and improve the performance of the catalysts towards CH4 conversion and C2+ yield. This review paper proposes employing a circulating reactor system coupled with catalyst fine particles but having little internal diffusion resistance to maximize one-pass C2+ selectivity and yield of the OCM reaction and evaluate its industrial application potential. 漏 2021 |
| 学科主题 | Ethylene |
| 项目编号 | This work has been supported by the Fund of National Key Research and Development Projects (Intergovernmental International Cooperation in Science and Technology Innovation Program, No. 2018YFE0103400 ), China. |
| 出版者 | KeAi Publishing Communications Ltd. |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/61210]  |
| 作者单位 | 1.Institute of Process Engineering, Chinese Academy of Sciences, Beijing; 100190, China 2.School of Ecology and Environment, Beijing Technology and Business University, Beijing; 100048, China 3.Institute of Industrial Chemistry and Energy Technology, Shenyang University of Chemical Technology, Shenyang; Liaoning; 110142, China |
| 推荐引用方式 GB/T 7714 | Liu, Jiao,Yue, Junrong,Lv, Mei,et al. From fundamentals to chemical engineering on oxidative coupling of methane for ethylene production: A review[J]. Carbon Resources Conversion,2022,5(1):44940. |
| APA | Liu, Jiao.,Yue, Junrong.,Lv, Mei.,Wang, Fang.,Cui, Yanbin.,...&Xu, Guangwen.(2022).From fundamentals to chemical engineering on oxidative coupling of methane for ethylene production: A review.Carbon Resources Conversion,5(1),44940. |
| MLA | Liu, Jiao,et al."From fundamentals to chemical engineering on oxidative coupling of methane for ethylene production: A review".Carbon Resources Conversion 5.1(2022):44940. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。