Insights into Ionic Liquids: From Z-Bonds to Quasi-Liquids
文献类型：期刊论文
| 作者 | Wang, Yanlei1,2; He, Hongyan1,2; Wang, Chenlu1,2; Lu, Yumiao2; Dong, Kun2; Huo, Feng2; Zhang, Suojiang1,2 |
| 刊名 | JACS Au
 |
| 出版日期 | 2022-03-28 |
| 卷号 | 2期号:3页码:543-561 |
| 关键词 | Bioconversion - Carbon dioxide - Computational chemistry - Environmental technology - Hydrogen bonds - Ionic liquids - Self assembly - Ultrathin films |
| DOI | 10.1021/jacsau.1c00538 |
| 英文摘要 | Ionic liquids (ILs) hold great promise in the fields of green chemistry, environmental science, and sustainable technology due to their unique properties, such as a tailorable structure, the various types available, and their environmentally friendly features. On the basis of multiscale simulations and experimental characterizations, two unique features of ILs are as follows: (1) strong coupling interactions between the electrostatic forces and hydrogen bonds, namely in the Z-bond, and (2) the unique semiordered structure and properties of ultrathin films, specifically regarding the quasi-liquid. In accordance with the aforementioned theoretical findings, many cutting-edge applications have been proposed: for example, CO2capture and conversion, biomass conversion and utilization, and energy storage materials. Although substantial progress has been made recently in the field of ILs, considerable challenges remain in understanding the nature of and devising applications for ILs, especially in terms of e.g. in situ/real-time observation and highly precise multiscale simulations of the Z-bond and quasi-liquid. In this Perspective, we review recent developments and challenges for the IL research community and provide insights into the nature and function of ILs, which will facilitate future applications. 漏 2022 American Chemical Society. All rights reserved. |
| 学科主题 | Sustainable Chemistry |
| 项目编号 | This research was funded by the National Key Research and Development Program of China (2021YFB3802600), the National Natural Science Foundation of China (21922813, 21890762, 22078322, 21834006 and 22178344), the Youth Innovation Promotion Association of CAS (2021046), the Fund of State Key Laboratory of Multiphase Complex Systems (MPCS-2021-A-7 and MPCS-2021-A-10), and the Innovation Academy for Green Manufacture, Chinese Academy of Sciences (IAGM2020C16). |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/61222]  |
| 作者单位 | 1.University of Chinese Academy of Sciences, Beijing; 100049, China 2.Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, CAS, Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing; 100190, China |
| 推荐引用方式 GB/T 7714 | Wang, Yanlei,He, Hongyan,Wang, Chenlu,et al. Insights into Ionic Liquids: From Z-Bonds to Quasi-Liquids[J]. JACS Au,2022,2(3):543-561. |
| APA | Wang, Yanlei.,He, Hongyan.,Wang, Chenlu.,Lu, Yumiao.,Dong, Kun.,...&Zhang, Suojiang.(2022).Insights into Ionic Liquids: From Z-Bonds to Quasi-Liquids.JACS Au,2(3),543-561. |
| MLA | Wang, Yanlei,et al."Insights into Ionic Liquids: From Z-Bonds to Quasi-Liquids".JACS Au 2.3(2022):543-561. |
入库方式： OAI收割
来源：过程工程研究所
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