Nano Cellulose Fibers and Graphene Oxide Coating on Polyolefin Separator With Uniform Li+ Transportation Channels for Long-Life and High-Safety Li Metal Battery
文献类型：期刊论文
| 作者 | Dai, Dongmei3; Chen, Yixuan2; Chen, Boran2; Qiu, Jinxu3; Li, Bao3; Wang, Bao1 |
| 刊名 | Journal of Electrochemical Energy Conversion and Storage
 |
| 出版日期 | 2022-02-01 |
| 卷号 | 19期号:1 |
| 关键词 | Anodes - Lithium batteries - Lithium - Electrochemical impedance spectroscopy - Graphene - Cellulose - Protective coatings |
| ISSN号 | 23816872 |
| DOI | 10.1115/1.4049043 |
| 英文摘要 | The lithium anode could greatly increase the energy density of the cell, but inevitable lithium dendrites hinder its application. A powerful coating layer can effectively suppress the growth of dendrite by promoting a fast and uniform Li+ flux. Here, a polyolefin separator coated with a layer of nano cellulose fiber (NCF) and graphene oxide (GO) is designed to restrain the growth of Li-dendrite and accommodate thermal shrinkage resistance. The results of electrochemical impedance spectroscopy showed that the NCF/GO coating with a mass ratio of 3:5 showed the highest value of ionic conductivity. The Li/separator/Li symmetrical battery with NCF/GO coated separator can work for 65 h during continuous charging before the voltage dropping down to zero, which is about 40% longer than the battery with bare polyolefin separator. In addition, the NCF/GO coating layer can also increase the retention capacity ratio of a cell by more than 10% in the 100 charge/discharge cycles. In this paper, the as-prepared NCF/GO coating separator provides a reference for designing a long-life and safety battery with Li-anode by effectively inhibiting the lithium dendrite. Copyright 漏 2021 by ASME |
| 学科主题 | Separators |
| 项目编号 | This work is financially supported by the National Natural Science Foundation of China (Nos. 51672071, 51802085, and 51772296), 111" Project (D17007) |
| 出版者 | American Society of Mechanical Engineers (ASME) |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/61270]  |
| 作者单位 | 1.State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing; 100190, China 2.School of Chemical Engineering and Technology, Tianjin University, Tianjin; 300072, China 3.Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang; 453007, China |
| 推荐引用方式 GB/T 7714 | Dai, Dongmei,Chen, Yixuan,Chen, Boran,et al. Nano Cellulose Fibers and Graphene Oxide Coating on Polyolefin Separator With Uniform Li+ Transportation Channels for Long-Life and High-Safety Li Metal Battery[J]. Journal of Electrochemical Energy Conversion and Storage,2022,19(1). |
| APA | Dai, Dongmei,Chen, Yixuan,Chen, Boran,Qiu, Jinxu,Li, Bao,&Wang, Bao.(2022).Nano Cellulose Fibers and Graphene Oxide Coating on Polyolefin Separator With Uniform Li+ Transportation Channels for Long-Life and High-Safety Li Metal Battery.Journal of Electrochemical Energy Conversion and Storage,19(1). |
| MLA | Dai, Dongmei,et al."Nano Cellulose Fibers and Graphene Oxide Coating on Polyolefin Separator With Uniform Li+ Transportation Channels for Long-Life and High-Safety Li Metal Battery".Journal of Electrochemical Energy Conversion and Storage 19.1(2022). |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。