Preparation of high ionic conductivity composite solid electrolyte with in-situ synthesis of LLZO@ZiF-67
文献类型：期刊论文
| 作者 | Yang, Xiaoyu2,3; Liu, Yanxia1,3; Li, Dezhao2,3; Dong, Jiayu3; Chai, Fengtao3; Yang, Baoyu2,3; Liu, Muhao2,3; Wang, Shuang2,3 |
| 刊名 | Electrochimica Acta
 |
| 出版日期 | 2022-11-01 |
| 卷号 | 431 |
| 关键词 | Fillers - Ionic conduction in solids - Ionic conductivity - Lithium - Lithium-ion batteries - Polyethylene oxides - Solid electrolytes - Solid state devices - Solid-State Batteries |
| ISSN号 | 134686 |
| DOI | 10.1016/j.electacta.2022.141155 |
| 英文摘要 | PEO based solid electrolyte has high crystallinity, which seriously hinder the transport of lithium ions at room temperature, resulting in low ionic conductivity. In this paper, a high performance composite solid electrolyte membrane with LLZO@ZiF-67 as an inorganic filler and PEO as matrix was synthesized. The LLZO@ZiF-67 inorganic filler, which covered by in-situ synthesis of ZiF-67 layer on surface of LLZO, show a large specific surface area and a polyhedral structure. The introduction of LLZO@ZiF-67 effectively reduce the crystallinity of PEO, providing a continuous channel for the transport of lithium ions, which result in a ionic conductivity as high as 1.09脳10鈭? S cm鈭? at room temperature of the composite electrolyte PLZ-20. Furthermore, the electrochemical stability and interface compatibility to lithium metal are improved. The lithium stripping/plating process at 0.1 mA cm鈭? can maintain stable for more than 600 h without short circuit. In addition, the initial discharge capacity of the full battery (Li / PLZ-20 / LFP) can reach up to 141.1 mA h g鈭? with retention of 91.45% after 100 cycles, which provide possibility for the application of high performance solid state battery. 漏 2022 |
| 学科主题 | Crystallinity |
| 项目编号 | This work was financially supported by the Key Science and Technology Special Project of Henan (project No. 202102210106), the Zhengzhou major Science and technology projects (project No. 2019CXZX0074). |
| 出版者 | Elsevier Ltd |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/61271]  |
| 作者单位 | 1.Beijing Key Laboratory of Ionic Liquids Clean Process, CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing; 100190, China 2.School of Chemical Engineering, Zhengzhou University, Zhengzhou; 450000, China 3.Henan Key Laboratory of Energy Storage Materials and Processes, Zhengzhou Institute of Emerging Industrial Technology, Zhengzhou; 450003, China |
| 推荐引用方式 GB/T 7714 | Yang, Xiaoyu,Liu, Yanxia,Li, Dezhao,et al. Preparation of high ionic conductivity composite solid electrolyte with in-situ synthesis of LLZO@ZiF-67[J]. Electrochimica Acta,2022,431. |
| APA | Yang, Xiaoyu.,Liu, Yanxia.,Li, Dezhao.,Dong, Jiayu.,Chai, Fengtao.,...&Wang, Shuang.(2022).Preparation of high ionic conductivity composite solid electrolyte with in-situ synthesis of LLZO@ZiF-67.Electrochimica Acta,431. |
| MLA | Yang, Xiaoyu,et al."Preparation of high ionic conductivity composite solid electrolyte with in-situ synthesis of LLZO@ZiF-67".Electrochimica Acta 431(2022). |
入库方式： OAI收割
来源：过程工程研究所
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