Selective Methacrolein Oxidation Catalyzed with Heteropoly Compounds: Effect of the Oxidation State Modulated with Hydrogen Pretreatment
文献类型：期刊论文
| 作者 | Yu, Jiayuan1,2; Yang, Yiqian3; Chen, Yu1; Wang, Lei1; Zhang, Guoliang1; Li, Chunshan1,2,4 |
| 刊名 | Industrial and Engineering Chemistry Research
 |
| 出版日期 | 2022-07-20 |
| 卷号 | 61期号:28页码:10014-10023 |
| 关键词 | Binary alloys - Catalysts - Chemical modification - Electron spin resonance spectroscopy - Hydrogen - Oxidation |
| ISSN号 | 8885885 |
| DOI | 10.1021/acs.iecr.2c01275 |
| 英文摘要 | The chemical state of catalysts is a vital factor affecting their catalytic performance. Herein, a method for controllable modification of the chemical state was proposed for the heteropoly catalyst in the methacrolein oxidation reaction to methacrylic acid by means of hydrogen pretreatment. The inherent relationship between the chemical state and the catalytic performance of the Keggin catalyst was systematically investigated. The changes in structure and element valence induced by hydrogen pretreatment were characterized with various methods, including XRD, FTIR, UV, Raman, SEM, O2-TPD, XPS, and ESR spectra. The pretreatment conditions were optimized on a fixed-bed tubular reactor, and the favored chemical state of the catalyst was obtained. This report provides an effective approach to activating the Keggin catalyst for oxidation reactions. 漏 2022 American Chemical Society. |
| 学科主题 | Fourier Transform Infrared Spectroscopy |
| 项目编号 | This work was financially supported by the National Natural Science Fund for Distinguished Young Scholars (no. 22025803), the Key Research and Development Program of Hebei Province (no. 20374002D) and the Innovation Academy for Green Manufacture of Chinese Academy of Sciences (IAGM-2019-A14). |
| 出版者 | American Chemical Society |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/61273]  |
| 作者单位 | 1.Cas Key Laboratory of Green Process and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing; 100190, China 2.Sino-Danish College, University of the Chinese Academy of Sciences, Beijing; 100049, China 3.School of Engineering and Technology, China University of Geosciences, Beijing; 100083, China 4.Zhengzhou Lnstitute of Emerging Industrial Technology, Zhengzhou; 450000, China |
| 推荐引用方式 GB/T 7714 | Yu, Jiayuan,Yang, Yiqian,Chen, Yu,et al. Selective Methacrolein Oxidation Catalyzed with Heteropoly Compounds: Effect of the Oxidation State Modulated with Hydrogen Pretreatment[J]. Industrial and Engineering Chemistry Research,2022,61(28):10014-10023. |
| APA | Yu, Jiayuan,Yang, Yiqian,Chen, Yu,Wang, Lei,Zhang, Guoliang,&Li, Chunshan.(2022).Selective Methacrolein Oxidation Catalyzed with Heteropoly Compounds: Effect of the Oxidation State Modulated with Hydrogen Pretreatment.Industrial and Engineering Chemistry Research,61(28),10014-10023. |
| MLA | Yu, Jiayuan,et al."Selective Methacrolein Oxidation Catalyzed with Heteropoly Compounds: Effect of the Oxidation State Modulated with Hydrogen Pretreatment".Industrial and Engineering Chemistry Research 61.28(2022):10014-10023. |
入库方式： OAI收割
来源：过程工程研究所
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