Rapid and solvent-free mechanochemical synthesis of Na iron hexacyanoferrate for high-performance Na-ion batteries
文献类型：期刊论文
| 作者 | Zhang, Peng2,3; Xu, Chunliu3; Zhao, Junmei3,4; Ma, Yongzhi3; Hu, Xin3; Hao, Lingyun2,3; Li, Xiaowei3; Yang, Yang1; Xu, Shuyin2; Liu, Huizhou3 |
| 刊名 | Materials Today Energy
 |
| 出版日期 | 2022-07-01 |
| 卷号 | 27 |
| 关键词 | Ball milling - Cathodes - Crystal structure - Hydrothermal synthesis - Iron - Iron compounds - Metal ions - Sodium compounds |
| DOI | 10.1016/j.mtener.2022.101027 |
| 英文摘要 | Sodium iron hexacyanoferrate (NaFeHCF) containing Fe as the only transition metal element has attained extensive interest for Na-ion batteries due to the low raw material cost and high resource abundance; however, the traditional solution-based synthesis methods, including coprecipitation and hydrothermal reaction, are usually time-consuming and difficult to control the interstitial water and Na content in the lattice, which puts a challenge on the high-efficiency and controllable preparation of NaFeHCF. Herein, we demonstrate a rapid and solvent-free mechanochemical route under the Ar atmosphere to synthesize Na1.59Fe[Fe(CN)6]0.950.051.92H2O cathode, which delivers an initial discharge capacity of 鈭?30 mA h g鈭? at 0.2 C and 118 mA h g鈭? at a high rate of 10 C. Besides, ex situ XRD confirms that NaFeHCF cathode experienced a phase transition from the initial cubic phase to Na-free cubic structure during the first charging process and followed by a reversible phase change between the monoclinic and Na-free cubic structures in the subsequent cycles. More impressively, the optimized NaFeHCF/NaTi2(PO4)3 full cell reveals a decent capacity retention of 80% over 1000 cycles at 1 C, exhibiting a promising prospect in the practical application. Our current work sheds light on the high-efficient scalable production of high-performance NaFeHCF cathodes for Na-ion batteries via mechanochemical approach. 漏 2022 Elsevier Ltd |
| 学科主题 | Sodium-ion Batteries |
| 项目编号 | P. Zhang and C. Xu contributed equally to this paper. J. Zhao designed this work. P. Zhang and C. Xu conducted the materials synthesis and electrochemical measurements. J. Zhao, C. Xu, S. Xu, and P. Zhang wrote the manuscripts. J. Zhao and S. Xu provided financial support. Y. Yang carried out the XPS measurements. All the authors participated in the analysis of the experimental data and discussions of the results, as well as in preparing the paper. |
| 出版者 | Elsevier Ltd |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/61304]  |
| 作者单位 | 1.Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing; 100190, China 2.Key Laboratory of Semiconductor Photovoltaic Technology of Inner Mongolia Autonomous Region, School of Physical Science and Technology, Inner Mongolia University, Hohhot; 010021, China 3.CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing; 100190, China 4.Innovation Academy for Green Manufacture, Chinese Academy of Sciences, Beijing; 100190, China |
| 推荐引用方式 GB/T 7714 | Zhang, Peng,Xu, Chunliu,Zhao, Junmei,et al. Rapid and solvent-free mechanochemical synthesis of Na iron hexacyanoferrate for high-performance Na-ion batteries[J]. Materials Today Energy,2022,27. |
| APA | Zhang, Peng.,Xu, Chunliu.,Zhao, Junmei.,Ma, Yongzhi.,Hu, Xin.,...&Hu, Yong-Sheng.(2022).Rapid and solvent-free mechanochemical synthesis of Na iron hexacyanoferrate for high-performance Na-ion batteries.Materials Today Energy,27. |
| MLA | Zhang, Peng,et al."Rapid and solvent-free mechanochemical synthesis of Na iron hexacyanoferrate for high-performance Na-ion batteries".Materials Today Energy 27(2022). |
入库方式： OAI收割
来源：过程工程研究所
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