Scalable synthesis of high-performance anode material SiOx/C for lithium-ion batteries by employing the Rochow reaction process
文献类型：期刊论文
| 作者 | Gao, Xingyue4,5; Gao, Yuan3; Li, Qiongguang2,4; Wang, Yanhong4; Zhao, Dawei5; Xu, Guangwen1,5; Zhong, Ziyi6,7; Su, Fabing1,4 |
| 刊名 | Journal of Alloys and Compounds
 |
| 出版日期 | 2022-05-05 |
| 卷号 | 902 |
| 关键词 | Ions - Copper compounds - Lithium-ion batteries - Silicon oxides - Silicon compounds |
| ISSN号 | 9258388 |
| DOI | 10.1016/j.jallcom.2022.163668 |
| 英文摘要 | The commercial application of silicon oxide (SiOx)-based anode materials in lithium-ion batteries (LIBs) is hindered by their poor electrochemical performance and difficulty in large-scale production. Here, we report a scalable synthesis of a carbon-coated SiOx composite (SiOx/C) as an excellent and stable anode material for LIBs. By employing the industrial Rochow reaction process, metallurgic grade Si microparticles first reacted with gaseous CH3OH over a Cu-based catalyst to generate alkoxysilanes (important organosilane monomers) and SiOx particles covered with organic compounds. After separation and washing, the obtained SiOx solid particles were carbonized to generate the SiOx/C composite. The prepared SiOx/C composite used as the anode material in LIBs could deliver a high reversible capacity of 581 mAh g鈭? at a higher current density of 100 mA g鈭? after 100 cycles and 510 mAh g鈭? after 250 cycles even at a higher current density of 500 mA g鈭?. It is anticipated that by employing an industrial process for alkoxysilane synthesis with controlled reaction conditions, the large-scale preparation of a SiOx/C anode material becomes highly feasible. 漏 2022 Elsevier B.V. |
| 学科主题 | Anodes |
| 项目编号 | The authors gratefully acknowledge the financial support provided by the National Natural Science Foundation of China (No. 51772295 ). Z. Zhong thanks the support of GTIIT for the collaboration. |
| 出版者 | Elsevier Ltd |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/61306]  |
| 作者单位 | 1.Institute of Industrial Chemistry and Energy Technology, Shenyang University of Chemical Technology, Shenyang; 110142, China 2.School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing; 100049, China 3.Ansteel Beijing Research Institute CO., LTD, Beijing; 102200, China 4.Institute of Process Engineering, Chinese Academy of Sciences, Beijing; 100190, China 5.Key Laboratory on Resources Chemicals and Materials of Ministry of Education, Shenyang University of Chemical Technology, Shenyang; 110142, China 6.Technion Israel Institute of Technology (IIT), Haifa, 32000, Israel 7.Department of Chemical Engineering, Guangdong Technion Israel Institute of Technology (GTIIT), 241 Daxue Road, Shantou; 515063, China |
| 推荐引用方式 GB/T 7714 | Gao, Xingyue,Gao, Yuan,Li, Qiongguang,et al. Scalable synthesis of high-performance anode material SiOx/C for lithium-ion batteries by employing the Rochow reaction process[J]. Journal of Alloys and Compounds,2022,902. |
| APA | Gao, Xingyue.,Gao, Yuan.,Li, Qiongguang.,Wang, Yanhong.,Zhao, Dawei.,...&Su, Fabing.(2022).Scalable synthesis of high-performance anode material SiOx/C for lithium-ion batteries by employing the Rochow reaction process.Journal of Alloys and Compounds,902. |
| MLA | Gao, Xingyue,et al."Scalable synthesis of high-performance anode material SiOx/C for lithium-ion batteries by employing the Rochow reaction process".Journal of Alloys and Compounds 902(2022). |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。