Electrodeposition of zinc coatings from the solutions of zinc oxide in imidazolium chloride/urea mixtures
文献类型：期刊论文
| 作者 | Zheng Yong1,2; Dong Kun1,2; Wang Qian1; Zhang SuoJiang1; Zhang QinQin1,2; Lu XingMei1 |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2012-08-01 |
| 卷号 | 55期号:8页码:1587-1597 |
| 关键词 | electrochemistry electroplating metal oxide zinc deposits ionic liquids |
| ISSN号 | 1674-7291 |
| 通讯作者 | Lu, XM |
| 英文摘要 | To solve the inherent disadvantages in conventional processes for electrodeposition of zinc, it's necessary to develop more high-efficiency and environmentally friendly electrolytes. In this work, it was found that the dissolution of ZnO was remarkably enhanced in some imidazolium chloride by the addition of urea, and the solubility of ZnO in 1:1 [Amim]Cl/urea mixture was as high as 8.35 wt% at 373.2 K. Electrochemical measurements showed that zinc could be readily electrodeposited from the solutions of ZnO. Bright, dense and well adherent zinc coatings with good purity were obtained from 0.6 M solution of ZnO in 1:1 [Amim]Cl/urea at 323.2-343.2 K. It's expected that the solutions of ZnO in imidazolium chloride/urea mixtures have the potential to replace the traditional electrolytes, especially toxic zinc chloride-based ones for zinc electroplating, as well as preparation of zinc materials. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | TEMPERATURE IONIC LIQUIDS ; SOLUBILIZING METAL-OXIDES ; CHOLINE CHLORIDE ; MOLTEN-SALT ; DICYANAMIDE ANION ; ALUMINUM ; SOLVENTS ; NUCLEATION ; DEPOSITION ; CATALYSIS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000307351500015 |
| 公开日期 | 2013-10-15 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/3259]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Coll Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng Yong,Dong Kun,Wang Qian,et al. Electrodeposition of zinc coatings from the solutions of zinc oxide in imidazolium chloride/urea mixtures[J]. SCIENCE CHINA-CHEMISTRY,2012,55(8):1587-1597. |
| APA | Zheng Yong,Dong Kun,Wang Qian,Zhang SuoJiang,Zhang QinQin,&Lu XingMei.(2012).Electrodeposition of zinc coatings from the solutions of zinc oxide in imidazolium chloride/urea mixtures.SCIENCE CHINA-CHEMISTRY,55(8),1587-1597. |
| MLA | Zheng Yong,et al."Electrodeposition of zinc coatings from the solutions of zinc oxide in imidazolium chloride/urea mixtures".SCIENCE CHINA-CHEMISTRY 55.8(2012):1587-1597. |
入库方式： OAI收割
来源：过程工程研究所
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