Equilibrium Solubility Modeling of CO2 in Na2Cr2O7 Solutions
文献类型：期刊论文
| 作者 | Zhou En-Nian1,2,3; Yu Zhi-Hui1,2 ; Qu Jing-Kui1,2; Qi Tao1,2; Han Xiao-Ying1,2,3; Zhang Guo-Qing4
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| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2012-11-01 |
| 卷号 | 28期号:11页码:2567-2573 |
| 关键词 | CO2 solubility Na2Cr2O7 solution Thermodynamic model Setschenow equation Peng-Robinson-Pitzer equation Henry constant |
| ISSN号 | 1000-6818 |
| 通讯作者 | Yu, ZH |
| 英文摘要 | The solubility of CO2 in aqueous Na2Cr2O7 solutions of different concentrations (0, 0.361, 0.650, and 0.901 mol.kg(-1)) was measured in a stirred vapor-liquid high-pressure equilibrium cell using the static method at temperatures and pressures in the ranges of 313.2 to 333.2 K and 0.1 to 1.9 MPa, respectively. The results indicated that the phenomenon of CO2 dissolved in aqueous Na2Cr2O7 could be interpreted according to a "salting-out effect". Furthermore, our solubility data for CO2 in aqueous Na2Cr2O7 was in agreement with Henry's law, and the Henry constant appeared to be a function of temperature, pressure, and the concentration of Na2Cr2O2. Two thermodynamic models were applied to correlate the experimental data, including the modified Setschenow and Peng-Robinson-Pitzer equations, and the averaged relative deviations were found to be 4.24% and 3.32%, respectively. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | CARBON-DIOXIDE ; OSMOTIC COEFFICIENTS ; THERMODYNAMICS ; ELECTROLYTES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000311597200008 |
| 公开日期 | 2013-10-10 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/3143]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 4.Sichuan Anxian YinHe Construct & Chem Grp Co Ltd, Anxian 622656, Sichuan Provinc, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou En-Nian,Yu Zhi-Hui,Qu Jing-Kui,et al. Equilibrium Solubility Modeling of CO2 in Na2Cr2O7 Solutions[J]. ACTA PHYSICO-CHIMICA SINICA,2012,28(11):2567-2573. |
| APA | Zhou En-Nian,Yu Zhi-Hui,Qu Jing-Kui,Qi Tao,Han Xiao-Ying,&Zhang Guo-Qing.(2012).Equilibrium Solubility Modeling of CO2 in Na2Cr2O7 Solutions.ACTA PHYSICO-CHIMICA SINICA,28(11),2567-2573. |
| MLA | Zhou En-Nian,et al."Equilibrium Solubility Modeling of CO2 in Na2Cr2O7 Solutions".ACTA PHYSICO-CHIMICA SINICA 28.11(2012):2567-2573. |
入库方式： OAI收割
来源：过程工程研究所
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