Chlorogallate(III) ionic liquids: Synthesis, acidity determination and their catalytic performances for isobutane alkylation
文献类型：期刊论文
| 作者 | Xing XueQi1,2; Zhao GuoYing1; Cui JianZhong2 |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2012-08-01 |
| 卷号 | 55期号:8页码:1542-1547 |
| 关键词 | chlorogallate(III) acidic ionic liquid Lewis acid alkylation isobutane |
| ISSN号 | 1674-7291 |
| 通讯作者 | Zhao, GY |
| 英文摘要 | A series of triethylammonium-based chlorogallate(III) ionic liquids with varied Lewis acidity was synthesized, characterized, and firstly applied to isobutane alkylation. The [Et3NHCl]-GaCl3 with = 0.65 displayed a potential catalytic activity for the alkylation. The addition of copper halide into the chlorogallate(III) ionic liquids dramatically enhanced the alkylation reaction. Up to 70.1% C-8 selectivity and 91.3 RON were achieved with the [Et3NHCl]-GaCl3-CuCl ( = 0.65, CuCl = 5% mol) under 0.5 MPa, 900 r/min, 15 min, 288 K using the industrial C-4 cut (isobutane/butene = 10). These results indicate that the chlorogallate(III) system may be used as a promising catalyst for the C-4 alkylation. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | CHLOROALUMINATE ; PERSPECTIVES ; CHLORIDE ; SYSTEMS ; BUTENE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000307351500009 |
| 公开日期 | 2013-10-15 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/3242]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 2.Tianjin Univ, Dept Chem, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xing XueQi,Zhao GuoYing,Cui JianZhong. Chlorogallate(III) ionic liquids: Synthesis, acidity determination and their catalytic performances for isobutane alkylation[J]. SCIENCE CHINA-CHEMISTRY,2012,55(8):1542-1547. |
| APA | Xing XueQi,Zhao GuoYing,&Cui JianZhong.(2012).Chlorogallate(III) ionic liquids: Synthesis, acidity determination and their catalytic performances for isobutane alkylation.SCIENCE CHINA-CHEMISTRY,55(8),1542-1547. |
| MLA | Xing XueQi,et al."Chlorogallate(III) ionic liquids: Synthesis, acidity determination and their catalytic performances for isobutane alkylation".SCIENCE CHINA-CHEMISTRY 55.8(2012):1542-1547. |
入库方式： OAI收割
来源：过程工程研究所
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