One-Dimensional 2r-d Conjugated Conductive Metal-Organic Framework with Dual Redox-Active Sites for High-Capacity and Durable Cathodes for Aqueous Zinc Batteries
文献类型：期刊论文
| 作者 | Sang, Zhiyuan1; Liu, Jiaxin1; Zhang, Xueqi1; Yin, Lichang2; Hou, Feng1; Liang, Ji1 |
| 刊名 | ACS NANO
 |
| 出版日期 | 2023-01-23 |
| 页码 | 11 |
| ISSN号 | 1936-0851 |
| 关键词 | ?-d conjugated metal-organic framework stable coordination structure electron ion transport dual redox-active sites aqueous Zn-based batteries |
| DOI | 10.1021/acsnano.2c11974 |
| 通讯作者 | Hou, Feng(houf@tju.edu.cn) ; Liang, Ji(liangji@tju.edu.cn) |
| 英文摘要 | advantages in terms of high safety, low cost, and environmental friendliness. However, the lack of suitable cathodes with highcapacity, long-cycling, and high-rate capability limits their practical application. Herein, we present a highly crystalline onedimensional 2r-d conjugated conductive metal-organic framework by coordinating ultrasmall 1,2,4,5-benzenetetramine (BTA) linkers with copper ions (Cu-BTA-H), as a cathode for ZIBs. The large ratio of active sites and dual redox mechanism of Cu-BTA-H, including the one-electron-redox reaction over copper ions (via Cu2+/Cu+) and the two-electron-redox reaction over organic ligands (via C=N/C-N), effectively enhance its reversible capacity. Meanwhile, the abundant porosity, small band gap, high crystallinity, and stable coordination structure of CuBTA-H endow it with fast ion/electron transport and effectively hinder the dissolution of organic ligands during cycling, respectively. Consequently, Cu-BTA-H possesses a high reversible capacity of 330 mAh g-1 at 200 mA g-1 and excellent rate performance and long-cycle stability, with a high capacity of 106.1 mAh g-1 at 2.0 A g-1 after 500 cycles and a high Coulombic efficiency of similar to 100%. The proposed conductive MOFs with dual redox-active sites provide an efficient approach for constructing fast, stable, and high-capacity energy storage devices. KEYWORDS: pi-d conjugated metal-organic framework, stable coordination structure, electron/ion transport, dual redox-active sites, |
| 资助项目 | Natural Science Foundation of China[22179093] ; Natural Science Foundation of China[21905202] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000922290500001 |
| 资助机构 | Natural Science Foundation of China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/175196]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Hou, Feng; Liang, Ji |
| 作者单位 | 1.Tianjin Univ, Sch Mat Sci & Engn, Key Lab Adv Ceram & Machining Technol, Minist Educ, Tianjin 300350, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sang, Zhiyuan,Liu, Jiaxin,Zhang, Xueqi,et al. One-Dimensional 2r-d Conjugated Conductive Metal-Organic Framework with Dual Redox-Active Sites for High-Capacity and Durable Cathodes for Aqueous Zinc Batteries[J]. ACS NANO,2023:11. |
| APA | Sang, Zhiyuan,Liu, Jiaxin,Zhang, Xueqi,Yin, Lichang,Hou, Feng,&Liang, Ji.(2023).One-Dimensional 2r-d Conjugated Conductive Metal-Organic Framework with Dual Redox-Active Sites for High-Capacity and Durable Cathodes for Aqueous Zinc Batteries.ACS NANO,11. |
| MLA | Sang, Zhiyuan,et al."One-Dimensional 2r-d Conjugated Conductive Metal-Organic Framework with Dual Redox-Active Sites for High-Capacity and Durable Cathodes for Aqueous Zinc Batteries".ACS NANO (2023):11. |
入库方式： OAI收割
来源：金属研究所
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