Highly efficient epoxidation of propylene to propylene oxide over TS-1 using urea plus hydrogen peroxide as oxidizing agent
文献类型：期刊论文
| 作者 | Cheng, Weiguo1,2; Wang, Xiangsheng2; Li, Gang2; Guo, Xinwen2; Zhang, Suojiang1 |
| 刊名 | JOURNAL OF CATALYSIS
 |
| 出版日期 | 2008-04-25 |
| 卷号 | 255期号:2页码:343-346 |
| 关键词 | epoxidation propylene propylene oxide urea hydrogen peroxide titanium silicate-1 electron paramagnetic resonance |
| ISSN号 | 0021-9517 |
| 其他题名 | J. Catal. |
| 中文摘要 | We compared the efficacies of urea + hydrogen peroxide (U+HP) and hydrogen peroxide (HP) as an oxidizing agent in the epoxidation of propylene catalyzed by a titanium silicate-1 (TS-1) molecular sieve. The TS-1 catalyst exhibited good performance and stability in the TS-1/(U+HP) system. EPR results showed that more active Ti-superoxo species led to better performance of TS-1 in the TS-1/(U+HP) system than in the TS-1/HP system. (c) 2008 Elsevier Inc. All rights reserved. |
| 英文摘要 | We compared the efficacies of urea + hydrogen peroxide (U+HP) and hydrogen peroxide (HP) as an oxidizing agent in the epoxidation of propylene catalyzed by a titanium silicate-1 (TS-1) molecular sieve. The TS-1 catalyst exhibited good performance and stability in the TS-1/(U+HP) system. EPR results showed that more active Ti-superoxo species led to better performance of TS-1 in the TS-1/(U+HP) system than in the TS-1/HP system. (c) 2008 Elsevier Inc. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | MOLECULAR-OXYGEN ; SELECTIVE EPOXIDATION ; CATALYSTS ; TITANIUM ; PROPENE ; COPPER ; H2O2 |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000255668200023 |
| 公开日期 | 2013-10-08 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/2729]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100080, Peoples R China 2.Dalian Univ Technol, Dept Catalysis Chem & Engn, State Key Lab Fine Chem, Dalian 116012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Weiguo,Wang, Xiangsheng,Li, Gang,et al. Highly efficient epoxidation of propylene to propylene oxide over TS-1 using urea plus hydrogen peroxide as oxidizing agent[J]. JOURNAL OF CATALYSIS,2008,255(2):343-346. |
| APA | Cheng, Weiguo,Wang, Xiangsheng,Li, Gang,Guo, Xinwen,&Zhang, Suojiang.(2008).Highly efficient epoxidation of propylene to propylene oxide over TS-1 using urea plus hydrogen peroxide as oxidizing agent.JOURNAL OF CATALYSIS,255(2),343-346. |
| MLA | Cheng, Weiguo,et al."Highly efficient epoxidation of propylene to propylene oxide over TS-1 using urea plus hydrogen peroxide as oxidizing agent".JOURNAL OF CATALYSIS 255.2(2008):343-346. |
入库方式： OAI收割
来源：过程工程研究所
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