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The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations

文献类型：期刊论文

作者Lu, Xingyu1,2; Qi, Ke1,2; Wang, Di1,2,3; Dai, Xueya1,2; Qi, Wei1,2
刊名CATALYSIS SCIENCE & TECHNOLOGY
出版日期2022-09-23
页码7
ISSN号2044-4753
DOI10.1039/d2cy01165d
通讯作者Qi, Wei(wqi@imr.ac.cn)
英文摘要2,5-Furandicarboxylic acid (FDCA) is a high-value platform molecule that can replace the fossil derivative terephthalic acid in the synthesis of important chemicals. FDCA can be synthesized from the oxidation of the biomass derivative 5-hydroxymethylfurfural (HMF). In this study, we loaded Cu-based catalysts with different morphologies and chemical states on carbon paper, and it was found that the Cu nanocrystalline/carbon paper catalyst with a thin and scattered dendrite structure (Cu(NSD)/CP) exhibits the best performance for the electrooxidation of HMF (96% yield and 100% selectivity for FDCA), which is attributed to the fact that the Cu-0 and Cu1+ species in the catalyst are easily oxidized in situ to Cu2+ species, showing high catalytic activity during the reaction process. This paper highlights the importance of the identification of active sites and the rational design of catalysts based on structure-function relations.
资助项目NSFC of China[22072163] ; Natural Science Foundation of Liaoning Province of China[2020-YQ-02] ; China Baowu Low Carbon Metallurgy Innovation[Foudation-BWLCF202113]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000865265600001
出版者ROYAL SOC CHEMISTRY
资助机构NSFC of China ; Natural Science Foundation of Liaoning Province of China ; China Baowu Low Carbon Metallurgy Innovation
源URL[http://ir.imr.ac.cn/handle/321006/176016]  
专题金属研究所_中国科学院金属研究所
通讯作者Qi, Wei
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China
3.Shenyang Pharmaceut Univ, Sch Pharm, Shenyang 110016, Peoples R China
推荐引用方式
GB/T 7714		 Lu, Xingyu,Qi, Ke,Wang, Di,et al. The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations[J]. CATALYSIS SCIENCE & TECHNOLOGY,2022:7.
APA Lu, Xingyu,Qi, Ke,Wang, Di,Dai, Xueya,&Qi, Wei.(2022).The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations.CATALYSIS SCIENCE & TECHNOLOGY,7.
MLA Lu, Xingyu,et al."The highly efficient electrocatalytic oxidation of 5-hydroxymethylfurfural on copper nanocrystalline/carbon hybrid catalysts: structure-function relations".CATALYSIS SCIENCE & TECHNOLOGY (2022):7.

入库方式： OAI收割

来源：金属研究所

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