Coordination polymer-derived non-precious metal catalyst for propane dehydrogenation: Highly dispersed zinc anchored on N-doped carbon
文献类型：期刊论文
| 作者 | Cao, Tianlong1,2; Dai, Xueya2,3; Fu, Yu1; Qi, Wei2,3 |
| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2023 |
| 卷号 | 607页码:11 |
| ISSN号 | 0169-4332 |
| 关键词 | Highly dispersed zinc sites Metal loading Coordination polymer Carbon nanosheet Propane dehydrogenation |
| DOI | 10.1016/j.apsusc.2022.155055 |
| 通讯作者 | Fu, Yu(fuyu@mail.neu.edu.cn) ; Qi, Wei(wqi@imr.ac.cn) |
| 英文摘要 | Highly dispersed non-precious metal catalysts supported on carbon have been intensively explored in the field of heterogeneous catalysis and material science owing to its low price, special electronic and geometric structure. However, their application and improvement of catalytic efficiency in alkane dehydrogenation were chronically limited due to spontaneous aggregation of metal atoms under the harsh conditions, low loading content and the complex preparation process. A new type of lamellar coordination polymer and a series of well-dispersed zinc -based catalyst anchored on N-doped carbon nanosheets were prepared via a facile combination of self-assembly and controlled pyrolysis. These carbonized composites showed superior initial activity (the propane conversion at 34% and the olefin selectivity at 80%) and acceptable catalytic stability (the deactivation rate of 0.082 h-1) in propane DDH reactions (600 degrees C, 2.4 kPa C3H8, He balance). The structure analysis results indicated the zinc loading in the optimized sample can be up to 19 wt%, which was also effectively retained after reactions. The systematic investigation on structure-function relations revealed that the catalytic activity originated from highly dispersed Zn, and the improvement of its performance could be ascribed to the mutual promotion between zinc loading and specific surface area. This work provided new guidelines to enable further development of the carbon-supported zinc-based catalyst in alkane dehydrogenation reactions and promoted the rational design of highly dispersed metal materials. |
| 资助项目 | National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province of China ; [22072163] ; [21761132010] ; [91645114] ; [2020-YQ-02] |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| WOS记录号 | WOS:000873701900002 |
| 资助机构 | National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province of China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/176303]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Fu, Yu; Qi, Wei |
| 作者单位 | 1.Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Tianlong,Dai, Xueya,Fu, Yu,et al. Coordination polymer-derived non-precious metal catalyst for propane dehydrogenation: Highly dispersed zinc anchored on N-doped carbon[J]. APPLIED SURFACE SCIENCE,2023,607:11. |
| APA | Cao, Tianlong,Dai, Xueya,Fu, Yu,&Qi, Wei.(2023).Coordination polymer-derived non-precious metal catalyst for propane dehydrogenation: Highly dispersed zinc anchored on N-doped carbon.APPLIED SURFACE SCIENCE,607,11. |
| MLA | Cao, Tianlong,et al."Coordination polymer-derived non-precious metal catalyst for propane dehydrogenation: Highly dispersed zinc anchored on N-doped carbon".APPLIED SURFACE SCIENCE 607(2023):11. |
入库方式： OAI收割
来源：金属研究所
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