Ultra-Dilute high-entropy alloy catalyst with core-shell structure for high-active hydrogenation of furfural to furfuryl alcohol at mild temperature
文献类型:期刊论文
作者 | Tu, Ren1; Liang, Kaili1; Sun, Yan1; Wu, Yangwen2; Lv, Wei3; Jia, Charles Q.4; Jiang, Enchen1; Wu, Yujian1; Fan, Xudong1; Zhang, Bing2 |
刊名 | CHEMICAL ENGINEERING JOURNAL |
出版日期 | 2023-01-15 |
卷号 | 452页码:11 |
ISSN号 | 1385-8947 |
关键词 | Furfural High-entropy alloy Ultra-dilute alloy Hydrogenation Core-shell structure |
DOI | 10.1016/j.cej.2022.139526 |
通讯作者 | Lu, Qiang(qianglu@mail.ustc.edu.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn) ; Xu, Xiwei(xuxiwei200801@hotmail.com) |
英文摘要 | Furfuryl Alcohol (FOL) from the catalytic hydrogenation of furfural represented a promising intermediate for industrial application. However, the high selectively of FOL in mild temperature was limited due to the over hydrogenation. Here, we synthesized the novel ultra-dilute high-entropy alloys (HEAs) with multiple metal sites and core-shell structure for boosting the selectivity of furfural hydrogenation to furfuryl alcohol. The results showed that the furfural was converted to FOL with the conversion of 87.32% and selectivity of 100% at 90 degrees C over ultra-dilute HEA (NiCoCuZnFe/C-800). The catalyst had redistribution of electrons between Cu (2.00) and atomically dispersed Zn (1.65) due to the different electronegativity. The electron-rich Cu repelled the furan ring and prevented the over hydrogenation, while the atomically dispersed Zn presented the strongest -CHO adsorption performance. Moreover, the core-shell structure enhanced the stability of the catalysts during hy-drogenation reaction and the porous carbon shell improved the transferring of furfural and electronic. |
资助项目 | Chinese National Natural Science Foundation ; Natural Science Foundation of Guangdong Province, China ; [52006074] ; [2021A1515010886] |
WOS研究方向 | Engineering |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE SA |
WOS记录号 | WOS:000871102700006 |
资助机构 | Chinese National Natural Science Foundation ; Natural Science Foundation of Guangdong Province, China |
源URL | [http://ir.imr.ac.cn/handle/321006/176328] |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Lu, Qiang; Zhang, Bingsen; Xu, Xiwei |
作者单位 | 1.South China Agr Univ, Coll Mat & Energy, Key Lab Biobased Mat & Energy, Minist Educ, Guangzhou 510640, Peoples R China 2.North China Elect Power Univ, Natl Engn Lab Biomass Power Generat Equipment, Beijing 102206, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Beijing, Peoples R China 4.Univ Toronto, Dept Chem Engn & Appl Chem, 200 Coll St, Toronto, ON M5S 3E5, Canada 5.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang, Peoples R China |
推荐引用方式 GB/T 7714 | Tu, Ren,Liang, Kaili,Sun, Yan,et al. Ultra-Dilute high-entropy alloy catalyst with core-shell structure for high-active hydrogenation of furfural to furfuryl alcohol at mild temperature[J]. CHEMICAL ENGINEERING JOURNAL,2023,452:11. |
APA | Tu, Ren.,Liang, Kaili.,Sun, Yan.,Wu, Yangwen.,Lv, Wei.,...&Xu, Xiwei.(2023).Ultra-Dilute high-entropy alloy catalyst with core-shell structure for high-active hydrogenation of furfural to furfuryl alcohol at mild temperature.CHEMICAL ENGINEERING JOURNAL,452,11. |
MLA | Tu, Ren,et al."Ultra-Dilute high-entropy alloy catalyst with core-shell structure for high-active hydrogenation of furfural to furfuryl alcohol at mild temperature".CHEMICAL ENGINEERING JOURNAL 452(2023):11. |
入库方式: OAI收割
来源:金属研究所
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