Design and Synthesis of a pi-Conjugated N-Heteroaromatic Material for Aqueous Zinc-Organic Batteries with Ultrahigh Rate and Extremely Long Life
文献类型：期刊论文
| 作者 | Li, Senlin1,2; Shang, Jian1,2; Li, Meilin1,2; Xu, Minwei1,2; Zeng, Fanbin1,2; Yin, Hang1,2; Tang, Yongbing1,2; Han, Cuiping1,2; Cheng, Hui-Ming1,2,3 |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2022-11-09 |
| 页码 | 11 |
| 关键词 | aqueous batteries N-heteroaromatic materials organic electrodes Zn-ion batteries Zn-organic batteries |
| ISSN号 | 0935-9648 |
| DOI | 10.1002/adma.202207115 |
| 通讯作者 | Han, Cuiping(cp.han@siat.ac.cn) ; Cheng, Hui-Ming(cheng@imr.ac.cn) |
| 英文摘要 | Electroactive organic materials with tailored functional groups are of great importance for aqueous Zn-organic batteries due to their green and renewable nature. Herein, a completely new N-heteroaromatic material, hexaazatrinaphthalene-phenazine (HATN-PNZ) is designed and synthesized, by an acid-catalyzed condensation reaction, and its use as an ultrahigh performance cathode for Zn-ion batteries demonstrated. Compared with phenazine monomer, it is revealed that the pi-conjugated structure of N-heteroaromatics can effectively increase electron delocalization, thereby improving its electrical conductivity. Furthermore, the enlarged aromatic structure noticeably suppresses its dissolution in aqueous electrolytes, thus enabling high structural stability. As expected, the HATN-PNZ cathode delivers a large reversible capacity of 257 mAh g(-1) at 5 A g(-1), ultrahigh rate capability of 144 mAh g(-1) at 100 A g(-1), and an extremely long cycle life of 45 000 cycles at 50 A g(-1). Investigation of the charge-storage mechanism demonstrates the synergistic coordination of both Zn2+ and H+ cations with the phenanthroline groups, with Zn2+ first followed by H+, accompanying the reversible formation of zinc hydroxide sulfate hydrate. This work provides a molecular-engineering strategy for superior organic materials and adds new insights to understand the charge-storage behavior of aqueous Zn-organic batteries. |
| 资助项目 | National Natural Science Foundation of China[22109134] ; National Natural Science Foundation of China[22279160] ; Guangdong Basic and Applied Basic Research Foundation[2022A1515010920] ; Science and Technology Foundation of Shenzhen[JCYJ20190808153609561] ; Open Research Found of Songshan Lake Materials Laboratory[2021SLABFN04] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000882559700001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; Guangdong Basic and Applied Basic Research Foundation ; Science and Technology Foundation of Shenzhen ; Open Research Found of Songshan Lake Materials Laboratory |
| 源URL | [http://ir.imr.ac.cn/handle/321006/176539]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Han, Cuiping; Cheng, Hui-Ming |
| 作者单位 | 1.Chinese Acad Sci, Shenzhen Inst Adv Technol, Inst Technol Carbon Neutral, Fac Mat Sci & Energy Engn, Shenzhen 518055, Peoples R China 2.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen Key Lab Energy Mat Carbon Neutral, Shenzhen 518055, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Senlin,Shang, Jian,Li, Meilin,et al. Design and Synthesis of a pi-Conjugated N-Heteroaromatic Material for Aqueous Zinc-Organic Batteries with Ultrahigh Rate and Extremely Long Life[J]. ADVANCED MATERIALS,2022:11. |
| APA | Li, Senlin.,Shang, Jian.,Li, Meilin.,Xu, Minwei.,Zeng, Fanbin.,...&Cheng, Hui-Ming.(2022).Design and Synthesis of a pi-Conjugated N-Heteroaromatic Material for Aqueous Zinc-Organic Batteries with Ultrahigh Rate and Extremely Long Life.ADVANCED MATERIALS,11. |
| MLA | Li, Senlin,et al."Design and Synthesis of a pi-Conjugated N-Heteroaromatic Material for Aqueous Zinc-Organic Batteries with Ultrahigh Rate and Extremely Long Life".ADVANCED MATERIALS (2022):11. |
入库方式： OAI收割
来源：金属研究所
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