Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties
文献类型：期刊论文
| 作者 | Li, Jingyu2,3; Zhao, Haichao1; Sui, Guoxin2,3 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2022-11-03 |
| 卷号 | 12期号:49页码:31699-31710 |
| DOI | 10.1039/d2ra05160e |
| 通讯作者 | Zhao, Haichao(zhaohaichao@nimte.ac.cn) ; Sui, Guoxin(gxsui@imr.ac.cn) |
| 英文摘要 | Hydrosilylation epoxidized eugenol (HSI-EP-EU) is successfully synthesized and used as a reactive diluent for epoxy/anhydride (marked as P) and epoxy/imidazole (marked as I) curing systems. The reactive bio-based diluent HSI-EP-EU has an excellent dilution effect on petroleum-based epoxy resin (E44). The curing kinetics of P + HSI-EP-EU and I + HSI-EP-EU are studied by a non-isothermal DSC method. The kinetics parameters are calculated by using the Kissinger model, Crnae model, Ozawa model and beta-T (temperature-heating speed) extrapolation, respectively, to determine theoretically reasonable curing conditions. In addition, the effects of HSI-EP-EU on the antibacterial properties, thermo-mechanical properties and thermal stability of P + HSI-EP-EU and I + HSI-EP-EU systems are also studied. It is found that HSI-EP-EU possessed obvious antibacterial properties and could effectively improve the mechanical properties for the I + HSI-EP-EU. |
| 资助项目 | Chinese Academy of Sciences-China[Y60707WR04] ; Zhejiang Key Research and Development Program[2022C01213] ; Graduate Innovation Research Fund of Institute of Metal Research, Chinese Academy of Sciences[1193002090] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000880759900001 |
| 资助机构 | Chinese Academy of Sciences-China ; Zhejiang Key Research and Development Program ; Graduate Innovation Research Fund of Institute of Metal Research, Chinese Academy of Sciences |
| 源URL | [http://ir.imr.ac.cn/handle/321006/176567]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Zhao, Haichao; Sui, Guoxin |
| 作者单位 | 1.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo 315201, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Jingyu,Zhao, Haichao,Sui, Guoxin. Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties[J]. RSC ADVANCES,2022,12(49):31699-31710. |
| APA | Li, Jingyu,Zhao, Haichao,&Sui, Guoxin.(2022).Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties.RSC ADVANCES,12(49),31699-31710. |
| MLA | Li, Jingyu,et al."Renewable green reactive diluent for bisphenol a epoxy resin system: curing kinetics and properties".RSC ADVANCES 12.49(2022):31699-31710. |
入库方式： OAI收割
来源：金属研究所
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