Fully Exposed Platinum Clusters on a Nanodiamond/Graphene Hybrid for Efficient Low-Temperature CO Oxidation
文献类型：期刊论文
| 作者 | Jia, Zhimin1,3; Peng, Mi4; Cai, Xiangbin5,6; Chen, Yunlei2,7; Chen, Xiaowen1,3; Huang, Fei3; Zhao, Linmin1,3; Diao, Jiangyong3; Wang, Ning5,6; Xiao, Dequan8 |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2022-07-22 |
| 页码 | 9 |
| 关键词 | CO oxidation nanodiamond Pt catalyst atomically dispersed cluster |
| ISSN号 | 2155-5435 |
| DOI | 10.1021/acscatal.2c02769 |
| 通讯作者 | Liu, Hongyang(liuhy@imr.ac.cn) ; Ma, Ding(dma@pku.edu.cn) |
| 英文摘要 | A fundamental understanding of the active sites in heterogeneous catalysts is extremely important in the development of effective catalysts. In general, it is difficult to identify the catalytically active sites due to their structural complexity, including the size and specific atomic configurations. In this paper, we prepare different Pt species (single atoms, fully exposed clusters, and nanoparticles) on a nanodiamond/graphene (ND@G) hybrid support to understand their evolution in structure for low-temperature CO oxidation. Remarkably, the atomically dispersed and fully exposed Pt clusters with an ensemble of a few Pt atoms showed the maximum atom utilization of low-coordinated metal sites. As determined by a catalytic performance evaluation, detailed characterizations, and theoretical calculations, the 0.5 wt % Pt-n/ND@G catalyst showed a catalytic performance for CO oxidation at low temperature superior to those of single-atom and nanoparticle catalysts, which was attributed to the weakened CO adsorption and facilitated O-2 dissociative adsorption on these atomically dispersed and fully exposed Pt cluster catalysts. |
| 资助项目 | National Key R&D Program of China[2021YFA1502802] ; National Natural Science Foundation of China[21961160722] ; National Natural Science Foundation of China[92145301] ; National Natural Science Foundation of China[U21B2092] ; National Natural Science Foundation of China[91845201] ; National Natural Science Foundation of China[22072162] ; National Natural Science Foundation of China[21725301] ; National Natural Science Foundation of China[21932002] ; Dalian National Lab for Clean Energy (DNL Cooperation Fund)[202001] ; Liaoning Revitalization Talents Program[XLYC1907055] ; Sinopec China[16306818] ; Research Grants Council of Hong Kong ; Hong Kong Branch of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; Beijing Synchrotron Radiation Facility (BSRF) |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000886009700001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Dalian National Lab for Clean Energy (DNL Cooperation Fund) ; Liaoning Revitalization Talents Program ; Sinopec China ; Research Grants Council of Hong Kong ; Hong Kong Branch of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; Beijing Synchrotron Radiation Facility (BSRF) |
| 源URL | [http://ir.imr.ac.cn/handle/321006/176767]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Liu, Hongyang; Ma, Ding |
| 作者单位 | 1.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 5.Hong Kong Univ Sci & Technol, Dept Phys, Hong Kong, Peoples R China 6.Hong Kong Univ Sci & Technol, Ctr Quantum Mat, Hong Kong, Peoples R China 7.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 8.Univ New Haven, Ctr Integrat Mat Discovery, Dept Chem & Chem Engn, West Haven, CT 06516 USA 9.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201204, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jia, Zhimin,Peng, Mi,Cai, Xiangbin,et al. Fully Exposed Platinum Clusters on a Nanodiamond/Graphene Hybrid for Efficient Low-Temperature CO Oxidation[J]. ACS CATALYSIS,2022:9. |
| APA | Jia, Zhimin.,Peng, Mi.,Cai, Xiangbin.,Chen, Yunlei.,Chen, Xiaowen.,...&Ma, Ding.(2022).Fully Exposed Platinum Clusters on a Nanodiamond/Graphene Hybrid for Efficient Low-Temperature CO Oxidation.ACS CATALYSIS,9. |
| MLA | Jia, Zhimin,et al."Fully Exposed Platinum Clusters on a Nanodiamond/Graphene Hybrid for Efficient Low-Temperature CO Oxidation".ACS CATALYSIS (2022):9. |
入库方式： OAI收割
来源：金属研究所
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