Modeling and simulation of materials synthesis: Chemical vapor deposition and infiltration of pyrolytic carbon
文献类型：期刊论文
| 作者 | Li, Aijun1; Norinaga, Koyo1,2; Zhang, Weigang1,3; Deutschmann, Olaf1 |
| 刊名 | COMPOSITES SCIENCE AND TECHNOLOGY
 |
| 出版日期 | 2008-04-01 |
| 卷号 | 68期号:5页码:1097-1104 |
| 关键词 | modeling computational simulation chemical vapor deposition chemical vapor infiltration |
| ISSN号 | 0266-3538 |
| 其他题名 | Compos. Sci. Technol. |
| 中文摘要 | Chemical vapor deposition and infiltration of pyrolytic carbon for the production of carbon fiber reinforced carbon is studied by modeling approaches and computational tools developed recently. Firstly, the development of a gas-phase reaction mechanism of chemical vapor deposition (CVD) of carbon from unsaturated light hydrocarbons (C2H4, C2H2, and C3H6) is presented. The mechanism consisting of 827 reactions among 227 species is based on existing information on elementary reactions and evaluated by comparison of numerically predicted and experimentally determined product compositions taking into account 44 stable gas-phase compounds formed in a tubular flow reactor. Secondly, a model and a computer code for two-dimensional transient simulations of chemical vapor infiltration (CVI) from methane into carbon fiber reinforced carbon are presented. The chemical model is based on a reduced multi-step reaction scheme for pyrolytic carbon deposition, which is derived from a mechanism based on elementary reactions, and a hydrogen inhibition model of pyrolytic carbon deposition. The coupled governing equations of mass transfer, chemical vapor deposition, surface growth, and gas-phase and surface chemical reactions are numerically solved by a finite element method (FEM). The computer code is applied to reveal densification processes of felts with fiber volume fractions of 7.1 % and 14.2%. Numerically predicted bulk density distributions agree well with experimental results. (c) 2007 Elsevier Ltd. All rights reserved. |
| 英文摘要 | Chemical vapor deposition and infiltration of pyrolytic carbon for the production of carbon fiber reinforced carbon is studied by modeling approaches and computational tools developed recently. Firstly, the development of a gas-phase reaction mechanism of chemical vapor deposition (CVD) of carbon from unsaturated light hydrocarbons (C2H4, C2H2, and C3H6) is presented. The mechanism consisting of 827 reactions among 227 species is based on existing information on elementary reactions and evaluated by comparison of numerically predicted and experimentally determined product compositions taking into account 44 stable gas-phase compounds formed in a tubular flow reactor. Secondly, a model and a computer code for two-dimensional transient simulations of chemical vapor infiltration (CVI) from methane into carbon fiber reinforced carbon are presented. The chemical model is based on a reduced multi-step reaction scheme for pyrolytic carbon deposition, which is derived from a mechanism based on elementary reactions, and a hydrogen inhibition model of pyrolytic carbon deposition. The coupled governing equations of mass transfer, chemical vapor deposition, surface growth, and gas-phase and surface chemical reactions are numerically solved by a finite element method (FEM). The computer code is applied to reveal densification processes of felts with fiber volume fractions of 7.1 % and 14.2%. Numerically predicted bulk density distributions agree well with experimental results. (c) 2007 Elsevier Ltd. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Materials Science, Composites |
| 研究领域[WOS] | Materials Science |
| 关键词[WOS] | PRESSURE-DEPENDENT MECHANISM ; CONVERSION ETHANE PYROLYSIS ; LOW-TEMPERATURE REGIME ; PYROCARBON DEPOSITION ; PREMIXED ACETYLENE ; LIGHT-HYDROCARBONS ; METHANE PYROLYSIS ; ETHYLENE ; FLAMES ; 1,3-BUTADIENE |
| 收录类别 | ISTP ; SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000255358900002 |
| 公开日期 | 2013-10-08 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/2785]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Univ Karlsruhe, Inst Tech Chem & Polymechem, D-76131 Karlsruhe, Germany 2.Hokkaido Univ, Ctr Adv Res Energy Convers Mat, Sapporo, Hokkaido 0608628, Japan 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Aijun,Norinaga, Koyo,Zhang, Weigang,et al. Modeling and simulation of materials synthesis: Chemical vapor deposition and infiltration of pyrolytic carbon[J]. COMPOSITES SCIENCE AND TECHNOLOGY,2008,68(5):1097-1104. |
| APA | Li, Aijun,Norinaga, Koyo,Zhang, Weigang,&Deutschmann, Olaf.(2008).Modeling and simulation of materials synthesis: Chemical vapor deposition and infiltration of pyrolytic carbon.COMPOSITES SCIENCE AND TECHNOLOGY,68(5),1097-1104. |
| MLA | Li, Aijun,et al."Modeling and simulation of materials synthesis: Chemical vapor deposition and infiltration of pyrolytic carbon".COMPOSITES SCIENCE AND TECHNOLOGY 68.5(2008):1097-1104. |
入库方式： OAI收割
来源：过程工程研究所
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