Sequence distribution effects on glass transition temperatures of copolymers: An extended Gibbs-DiMarzio equation in view of bond rotation flexibility
文献类型：期刊论文
| 作者 | Liu, G. D. ; Meng, Z. Y. ; Wang, W. ; Zhou, Y. L. ; Zhangt, L. C. |
| 刊名 | Journal of Physical Chemistry B
 |
| 出版日期 | 2008 |
| 期号 | 1页码:93-99 |
| 关键词 | equimolar copolymers ordered copolymers acrylonitrile |
| 其他题名 | J. Phys. Chem. B |
| 中文摘要 | In view of bond rotation flexibility and the additivity of stiff energy, a new equation containing mole fractions of sequences and glass transition temperatures (T-g's) of periodic copolymers was proposed. Meanwhile, the effect of stereochemical sequences was also taken into account. Even for the case of all substitutions on primary (C-1), second (C-2) and third (C-3) carbon atoms adjoining to the given bond (triad sequences effect) to be considered, no intractable parameters exist in the new equation if the periodic copolymers of poly[AB], poly[AAB], and poly[BBA] could be acquired. This may facilitate its convenient application in comparison with the Ham equation (Ham, G. E. J. Macromol. Sci. Chem. 1975, A9, 461), which also concerned triad contributions. The new equation was applied to methyl methacrylate-styrene, ethylene-methyl methacrylate, and ethylene-vinyl acetate copolymers, and excellent fittings were obtained. The parameters obtained may predict T, values of periodic copolymers that have not been acquired as well as provide useful information on the bond rotation flexibility. |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000252122400013 |
| 公开日期 | 2013-10-08 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/2804]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 推荐引用方式 GB/T 7714 | Liu, G. D.,Meng, Z. Y.,Wang, W.,et al. Sequence distribution effects on glass transition temperatures of copolymers: An extended Gibbs-DiMarzio equation in view of bond rotation flexibility[J]. Journal of Physical Chemistry B,2008(1):93-99. |
| APA | Liu, G. D.,Meng, Z. Y.,Wang, W.,Zhou, Y. L.,&Zhangt, L. C..(2008).Sequence distribution effects on glass transition temperatures of copolymers: An extended Gibbs-DiMarzio equation in view of bond rotation flexibility.Journal of Physical Chemistry B(1),93-99. |
| MLA | Liu, G. D.,et al."Sequence distribution effects on glass transition temperatures of copolymers: An extended Gibbs-DiMarzio equation in view of bond rotation flexibility".Journal of Physical Chemistry B .1(2008):93-99. |
入库方式： OAI收割
来源：过程工程研究所
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