Synthesis and spectral characteristic of Ga-Fe3O4 at room temperature
文献类型：期刊论文
| 作者 | Wang Jing1,2; Deng Tong2; Yang Cai-qin1; Lin Yu-long1; Wang Wei1; Wu Hai-yan1 |
| 刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
 |
| 出版日期 | 2008-03-01 |
| 卷号 | 28期号:3页码:715-718 |
| 关键词 | gallium magnetite XRD IR Mossbauer spectra |
| ISSN号 | 1000-0593 |
| 其他题名 | Spectrosc. Spectr. Anal. |
| 中文摘要 | Gallium bearing ferrites with different gallium content were synthesized by oxidation of ferrous and gallium ions under alkaline condition and room temperature. The samples were subjected to IR, XRD, Mossbauer spectral analysis and magnetization characterization. The results indicated that the green-rust intermediate phase would be produced during the procedure of GaFe3O4 formation, and the green-rust intermediate phase was converted to ferrites with spinel structure during the drying under hot-N-2 atmosphere. With the introduction of gallium into the spinel structure, the interplanar crystal spacing of the spinel structure decreased, as indicated from XRD spectra, and the lattice vibration of M-T-O-M-O moved to the high-frequency resulting from IR spectra. A small amount gallium introduction entered the tetrahedral sites preferentially rather than the octahedral sites, and increasing gallium introduction would enhance the occupation of octahedral sites. Furthermore, a small content of gallium in the initial solution could prevent the formation of non-magnetic Fe2O3. |
| 英文摘要 | Gallium bearing ferrites with different gallium content were synthesized by oxidation of ferrous and gallium ions under alkaline condition and room temperature. The samples were subjected to IR, XRD, Mossbauer spectral analysis and magnetization characterization. The results indicated that the green-rust intermediate phase would be produced during the procedure of GaFe3O4 formation, and the green-rust intermediate phase was converted to ferrites with spinel structure during the drying under hot-N-2 atmosphere. With the introduction of gallium into the spinel structure, the interplanar crystal spacing of the spinel structure decreased, as indicated from XRD spectra, and the lattice vibration of M-T-O-M-O moved to the high-frequency resulting from IR spectra. A small amount gallium introduction entered the tetrahedral sites preferentially rather than the octahedral sites, and increasing gallium introduction would enhance the occupation of octahedral sites. Furthermore, a small content of gallium in the initial solution could prevent the formation of non-magnetic Fe2O3. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Spectroscopy |
| 研究领域[WOS] | Spectroscopy |
| 关键词[WOS] | BEARING FERRITE PARTICLES ; GA SUBSTITUTED MAGNETITE ; WASTE-WATER ; MOSSBAUER |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000256273800058 |
| 公开日期 | 2013-10-08 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/2858]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Hebei Med Univ, Sch Pharmaceut Sci, Shijiazhuang 050017, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Jing,Deng Tong,Yang Cai-qin,et al. Synthesis and spectral characteristic of Ga-Fe3O4 at room temperature[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2008,28(3):715-718. |
| APA | Wang Jing,Deng Tong,Yang Cai-qin,Lin Yu-long,Wang Wei,&Wu Hai-yan.(2008).Synthesis and spectral characteristic of Ga-Fe3O4 at room temperature.SPECTROSCOPY AND SPECTRAL ANALYSIS,28(3),715-718. |
| MLA | Wang Jing,et al."Synthesis and spectral characteristic of Ga-Fe3O4 at room temperature".SPECTROSCOPY AND SPECTRAL ANALYSIS 28.3(2008):715-718. |
入库方式： OAI收割
来源：过程工程研究所
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