Selective Electrochemical Benzylic C(sp(3))-H Oxidations in Fluoroalcohols
文献类型：期刊论文
| 作者 | Shen, Haiwei1,2; Yang, Bo1; Lin, Jiusheng1; Zheng, Mingyue1,2 ; Jiang, Hualiang1,2
|
| 刊名 | CHEMISTRYSELECT
 |
| 出版日期 | 2023-07-20 |
| 卷号 | 8期号:27页码:4 |
| ISSN号 | 2365-6549 |
| 关键词 | C(sp(3))-H oxidation electrochemical aryl aldehydes fluorinated ethers eco-friendly |
| DOI | 10.1002/slct.202302073 |
| 通讯作者 | Shen, Haiwei() ; Zheng, Mingyue(myzheng@simm.ac.cn) ; Jiang, Hualiang(hljiang@simm.ac.cn) |
| 英文摘要 | A site-selective electrochemical benzylic C(sp(3))-H oxidation reaction of aryl alkanes has been reported for synthesis of the desired products. This method significantly expands the scope and enhances the selectivity of aryl aldehydes and fluorinated ethers. Electricity is used as a sustainable oxidant and promote H-2 evolution. This protocol is eco-friendly and easy to handle as it uses a simple undivided cell in mild conditions without employing any catalyst and oxidant. |
| WOS关键词 | C-H OXIDATION ; N-HYDROXYPHTHALIMIDE ; METAL-FREE ; ALKYLARENES ; ACTIVATION ; METHYLARENES ; KETONES ; OXYGEN |
| 资助项目 | China Postdoctoral Science Foundation[2021M703351] ; National Natural Science Foundation of China[82273855] ; Lingang Laboratory[LG202102-01] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:001031864200001 |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/306734]  |
| 专题 | 新药研究国家重点实验室 |
| 通讯作者 | Shen, Haiwei; Zheng, Mingyue; Jiang, Hualiang |
| 作者单位 | 1.Univ Chinese Acad Sci, Hangzhou Inst Adv Study, Sch Pharmacol Sci & Technol, Hangzhou, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Mat Med, Drug Discovery & Design Ctr, State Key Lab Drug Res, Shanghai, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, Haiwei,Yang, Bo,Lin, Jiusheng,et al. Selective Electrochemical Benzylic C(sp(3))-H Oxidations in Fluoroalcohols[J]. CHEMISTRYSELECT,2023,8(27):4. |
| APA | Shen, Haiwei,Yang, Bo,Lin, Jiusheng,Zheng, Mingyue,&Jiang, Hualiang.(2023).Selective Electrochemical Benzylic C(sp(3))-H Oxidations in Fluoroalcohols.CHEMISTRYSELECT,8(27),4. |
| MLA | Shen, Haiwei,et al."Selective Electrochemical Benzylic C(sp(3))-H Oxidations in Fluoroalcohols".CHEMISTRYSELECT 8.27(2023):4. |
入库方式： OAI收割
来源：上海药物研究所
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